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Article: Flexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks
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TitleFlexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks
 
AuthorsHuang, G3
Tsang, CK3
Xu, Z3
Li, K1
Zeller, M4
Hunter, AD4
Chui, SSY2
Che, CM2
 
Issue Date2009
 
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/crystal
 
CitationCrystal Growth And Design, 2009, v. 9 n. 3, p. 1444-1451 [How to Cite?]
DOI: http://dx.doi.org/10.1021/cg800869u
 
AbstractFrom searching the Cambridge Structural Database (CSD), we noticed an exceptionally widespread distribution of the interatomic distances (from 2.39 to 3.52 Å) between thioether S atoms and Ag(I) ions, in comparison with the cases in other common ligands such as nitriles and pyridyls. The variable bonding distances point to a highly flexible and reversible nature of thioether-Ag(I) interaction, which might help crystallize large and complex organic molecules into ordered coordination networks under mild conditions. We provide a number of new structures for illustration. In 1, two Ag(I) ions are coordinated by three 1,2,3- tris(methylthio)phenyl groups (i.e., 9 S atoms) to form a three-bladed paddlewheel block as a node for an enlarged honeycomb sheet. In 2, a porphyrin molecule with four l,2,3-tris(phenylthio)phenyl groups coordinates to Ag(I) atoms to form a parallelogram net, featuring free-standing phenylthio groups in the channel. In 3, a starburst molecule with six 4-methylthiophenyl groups attached to the triphenylene core is crystallized with AgOTf (triflate) to form a complex three-dimensional net, with a supramolecular topology featuring a combination of edge-sharing octahedra (the rutile chain) and vertex-sharing octahedra (the ReO 3 chain). © 2009 American Chemical Society.
 
ISSN1528-7483
2013 Impact Factor: 4.558
 
DOIhttp://dx.doi.org/10.1021/cg800869u
 
ISI Accession Number IDWOS:000263921300037
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, China9041212
CityU103407
NSF0087210
Ohio Board of RegentsCAP-491
Funding Information:

This work is supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China [Project No. 9041212 (CityU 103407)]. The diffractometer was funded by NSF Grant 0087210, by the Ohio Board of Regents grant CAP-491, and by YSU.

 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorHuang, G
 
dc.contributor.authorTsang, CK
 
dc.contributor.authorXu, Z
 
dc.contributor.authorLi, K
 
dc.contributor.authorZeller, M
 
dc.contributor.authorHunter, AD
 
dc.contributor.authorChui, SSY
 
dc.contributor.authorChe, CM
 
dc.date.accessioned2010-05-31T03:29:10Z
 
dc.date.available2010-05-31T03:29:10Z
 
dc.date.issued2009
 
dc.description.abstractFrom searching the Cambridge Structural Database (CSD), we noticed an exceptionally widespread distribution of the interatomic distances (from 2.39 to 3.52 Å) between thioether S atoms and Ag(I) ions, in comparison with the cases in other common ligands such as nitriles and pyridyls. The variable bonding distances point to a highly flexible and reversible nature of thioether-Ag(I) interaction, which might help crystallize large and complex organic molecules into ordered coordination networks under mild conditions. We provide a number of new structures for illustration. In 1, two Ag(I) ions are coordinated by three 1,2,3- tris(methylthio)phenyl groups (i.e., 9 S atoms) to form a three-bladed paddlewheel block as a node for an enlarged honeycomb sheet. In 2, a porphyrin molecule with four l,2,3-tris(phenylthio)phenyl groups coordinates to Ag(I) atoms to form a parallelogram net, featuring free-standing phenylthio groups in the channel. In 3, a starburst molecule with six 4-methylthiophenyl groups attached to the triphenylene core is crystallized with AgOTf (triflate) to form a complex three-dimensional net, with a supramolecular topology featuring a combination of edge-sharing octahedra (the rutile chain) and vertex-sharing octahedra (the ReO 3 chain). © 2009 American Chemical Society.
 
dc.description.naturelink_to_subscribed_fulltext
 
dc.identifier.citationCrystal Growth And Design, 2009, v. 9 n. 3, p. 1444-1451 [How to Cite?]
DOI: http://dx.doi.org/10.1021/cg800869u
 
dc.identifier.doihttp://dx.doi.org/10.1021/cg800869u
 
dc.identifier.epage1451
 
dc.identifier.hkuros156010
 
dc.identifier.isiWOS:000263921300037
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, China9041212
CityU103407
NSF0087210
Ohio Board of RegentsCAP-491
Funding Information:

This work is supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China [Project No. 9041212 (CityU 103407)]. The diffractometer was funded by NSF Grant 0087210, by the Ohio Board of Regents grant CAP-491, and by YSU.

 
dc.identifier.issn1528-7483
2013 Impact Factor: 4.558
 
dc.identifier.issue3
 
dc.identifier.openurl
 
dc.identifier.scopuseid_2-s2.0-65249155869
 
dc.identifier.spage1444
 
dc.identifier.urihttp://hdl.handle.net/10722/58373
 
dc.identifier.volume9
 
dc.languageeng
 
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/crystal
 
dc.publisher.placeUnited States
 
dc.relation.ispartofCrystal Growth and Design
 
dc.relation.referencesReferences in Scopus
 
dc.titleFlexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks
 
dc.typeArticle
 
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<contributor.author>Zeller, M</contributor.author>
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<contributor.author>Che, CM</contributor.author>
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Author Affiliations
  1. George Washington University
  2. The University of Hong Kong
  3. City University of Hong Kong
  4. Youngstown State University