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Article: Flexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks

TitleFlexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networks
Authors
Issue Date2009
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/crystal
Citation
Crystal Growth And Design, 2009, v. 9 n. 3, p. 1444-1451 How to Cite?
AbstractFrom searching the Cambridge Structural Database (CSD), we noticed an exceptionally widespread distribution of the interatomic distances (from 2.39 to 3.52 Å) between thioether S atoms and Ag(I) ions, in comparison with the cases in other common ligands such as nitriles and pyridyls. The variable bonding distances point to a highly flexible and reversible nature of thioether-Ag(I) interaction, which might help crystallize large and complex organic molecules into ordered coordination networks under mild conditions. We provide a number of new structures for illustration. In 1, two Ag(I) ions are coordinated by three 1,2,3- tris(methylthio)phenyl groups (i.e., 9 S atoms) to form a three-bladed paddlewheel block as a node for an enlarged honeycomb sheet. In 2, a porphyrin molecule with four l,2,3-tris(phenylthio)phenyl groups coordinates to Ag(I) atoms to form a parallelogram net, featuring free-standing phenylthio groups in the channel. In 3, a starburst molecule with six 4-methylthiophenyl groups attached to the triphenylene core is crystallized with AgOTf (triflate) to form a complex three-dimensional net, with a supramolecular topology featuring a combination of edge-sharing octahedra (the rutile chain) and vertex-sharing octahedra (the ReO 3 chain). © 2009 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/58373
ISSN
2014 Impact Factor: 4.891
ISI Accession Number ID
Funding AgencyGrant Number
Research Grants Council of the Hong Kong Special Administrative Region, China9041212
CityU103407
NSF0087210
Ohio Board of RegentsCAP-491
Funding Information:

This work is supported by a grant from the Research Grants Council of the Hong Kong Special Administrative Region, China [Project No. 9041212 (CityU 103407)]. The diffractometer was funded by NSF Grant 0087210, by the Ohio Board of Regents grant CAP-491, and by YSU.

References

 

DC FieldValueLanguage
dc.contributor.authorHuang, Gen_HK
dc.contributor.authorTsang, CKen_HK
dc.contributor.authorXu, Zen_HK
dc.contributor.authorLi, Ken_HK
dc.contributor.authorZeller, Men_HK
dc.contributor.authorHunter, ADen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2010-05-31T03:29:10Z-
dc.date.available2010-05-31T03:29:10Z-
dc.date.issued2009en_HK
dc.identifier.citationCrystal Growth And Design, 2009, v. 9 n. 3, p. 1444-1451en_HK
dc.identifier.issn1528-7483en_HK
dc.identifier.urihttp://hdl.handle.net/10722/58373-
dc.description.abstractFrom searching the Cambridge Structural Database (CSD), we noticed an exceptionally widespread distribution of the interatomic distances (from 2.39 to 3.52 Å) between thioether S atoms and Ag(I) ions, in comparison with the cases in other common ligands such as nitriles and pyridyls. The variable bonding distances point to a highly flexible and reversible nature of thioether-Ag(I) interaction, which might help crystallize large and complex organic molecules into ordered coordination networks under mild conditions. We provide a number of new structures for illustration. In 1, two Ag(I) ions are coordinated by three 1,2,3- tris(methylthio)phenyl groups (i.e., 9 S atoms) to form a three-bladed paddlewheel block as a node for an enlarged honeycomb sheet. In 2, a porphyrin molecule with four l,2,3-tris(phenylthio)phenyl groups coordinates to Ag(I) atoms to form a parallelogram net, featuring free-standing phenylthio groups in the channel. In 3, a starburst molecule with six 4-methylthiophenyl groups attached to the triphenylene core is crystallized with AgOTf (triflate) to form a complex three-dimensional net, with a supramolecular topology featuring a combination of edge-sharing octahedra (the rutile chain) and vertex-sharing octahedra (the ReO 3 chain). © 2009 American Chemical Society.en_HK
dc.languageengen_HK
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/crystalen_HK
dc.relation.ispartofCrystal Growth and Designen_HK
dc.titleFlexible thioether-Ag(I) interactions for assembling large organic ligands into crystalline networksen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=1528-7483&volume=9&spage=1444&epage=1451&date=2009&atitle=Flexible+Thioether-Ag(I)+Interactions+for+Assembling+Large+Organic+Ligands+into+Crystalline+Networksen_HK
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/cg800869uen_HK
dc.identifier.scopuseid_2-s2.0-65249155869en_HK
dc.identifier.hkuros156010en_HK
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-65249155869&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume9en_HK
dc.identifier.issue3en_HK
dc.identifier.spage1444en_HK
dc.identifier.epage1451en_HK
dc.identifier.isiWOS:000263921300037-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridHuang, G=36984730800en_HK
dc.identifier.scopusauthoridTsang, CK=25032030900en_HK
dc.identifier.scopusauthoridXu, Z=9843801700en_HK
dc.identifier.scopusauthoridLi, K=55487992100en_HK
dc.identifier.scopusauthoridZeller, M=8518298000en_HK
dc.identifier.scopusauthoridHunter, AD=7402779700en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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