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Article: Pd(II)-Catalyzed Enantioselective C(sp3)-H Borylation

TitlePd(II)-Catalyzed Enantioselective C(sp3)-H Borylation
Authors
He, JianShao, QianWu, QingfengYu, Jin Quan
Issue Date2017
Citation
Journal of the American Chemical Society, 2017, v. 139, n. 9, p. 3344-3347 How to Cite?
DOI: http://dx.doi.org/10.1021/jacs.6b13389
Abstract© 2017 American Chemical Society. Pd(II)-catalyzed enantioselective borylation of C(sp3)-H bonds has been realized for the first time using chiral acetyl-protected aminomethyl oxazoline ligands. This reaction is compatible with carbocyclic amides containing α-tertiary as well as α-quaternary carbon centers. The chiral β-borylated amides are useful synthons for the synthesis of chiral β-hydroxylated, β-fluorinated, and β-arylated carboxylic acids.
Persistent Identifierhttp://hdl.handle.net/10722/277063
ISSN
0002-7863
2021 Impact Factor: 16.383
2020 SCImago Journal Rankings: 7.115
ISI Accession Number ID
WOS:000396185700010

 

DC FieldValueLanguage
dc.contributor.authorHe, Jian-
dc.contributor.authorShao, Qian-
dc.contributor.authorWu, Qingfeng-
dc.contributor.authorYu, Jin Quan-
dc.date.accessioned2019-09-18T08:35:29Z-
dc.date.available2019-09-18T08:35:29Z-
dc.date.issued2017-
dc.identifier.citationJournal of the American Chemical Society, 2017, v. 139, n. 9, p. 3344-3347-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/277063-
dc.description.abstract© 2017 American Chemical Society. Pd(II)-catalyzed enantioselective borylation of C(sp3)-H bonds has been realized for the first time using chiral acetyl-protected aminomethyl oxazoline ligands. This reaction is compatible with carbocyclic amides containing α-tertiary as well as α-quaternary carbon centers. The chiral β-borylated amides are useful synthons for the synthesis of chiral β-hydroxylated, β-fluorinated, and β-arylated carboxylic acids.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titlePd(II)-Catalyzed Enantioselective C(sp3)-H Borylation-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jacs.6b13389-
dc.identifier.pmid28209055-
dc.identifier.scopuseid_2-s2.0-85014726421-
dc.identifier.volume139-
dc.identifier.issue9-
dc.identifier.spage3344-
dc.identifier.epage3347-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000396185700010-
dc.identifier.issnl0002-7863-

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