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Article: CuCl-catalyzed stereoselective conjugate addition of Grignard reagents to 2,3-allenoates

TitleCuCl-catalyzed stereoselective conjugate addition of Grignard reagents to 2,3-allenoates
Authors
He, JianLu, ZhanChai, GuobiFu, ChunlingMa, Shengming
KeywordsConjugate addition
Copper-catalysis
Grignard reagents
2,3-Allenoates
Issue Date2012
Citation
Tetrahedron, 2012, v. 68, n. 12, p. 2719-2724 How to Cite?
DOI: http://dx.doi.org/10.1016/j.tet.2012.01.027
AbstractCuCl was found to be an efficient catalyst for the conjugate addition of 2,3-allenoates with Grignard reagents to synthesize poly-substituted β,γ-unsaturated alkenoates with high stereoselectivity in good to excellent yields. Primary, secondary, and tertiary alkyl, vinyl or phenyl Grignard reagents may all be used. © 2012 Elsevier Ltd. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/276915
ISSN
0040-4020
2021 Impact Factor: 2.388
2020 SCImago Journal Rankings: 0.581
ISI Accession Number ID
WOS:000301692700019

 

DC FieldValueLanguage
dc.contributor.authorHe, Jian-
dc.contributor.authorLu, Zhan-
dc.contributor.authorChai, Guobi-
dc.contributor.authorFu, Chunling-
dc.contributor.authorMa, Shengming-
dc.date.accessioned2019-09-18T08:35:02Z-
dc.date.available2019-09-18T08:35:02Z-
dc.date.issued2012-
dc.identifier.citationTetrahedron, 2012, v. 68, n. 12, p. 2719-2724-
dc.identifier.issn0040-4020-
dc.identifier.urihttp://hdl.handle.net/10722/276915-
dc.description.abstractCuCl was found to be an efficient catalyst for the conjugate addition of 2,3-allenoates with Grignard reagents to synthesize poly-substituted β,γ-unsaturated alkenoates with high stereoselectivity in good to excellent yields. Primary, secondary, and tertiary alkyl, vinyl or phenyl Grignard reagents may all be used. © 2012 Elsevier Ltd. All rights reserved.-
dc.languageeng-
dc.relation.ispartofTetrahedron-
dc.subjectConjugate addition-
dc.subjectCopper-catalysis-
dc.subjectGrignard reagents-
dc.subject2,3-Allenoates-
dc.titleCuCl-catalyzed stereoselective conjugate addition of Grignard reagents to 2,3-allenoates-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.tet.2012.01.027-
dc.identifier.scopuseid_2-s2.0-84857631115-
dc.identifier.volume68-
dc.identifier.issue12-
dc.identifier.spage2719-
dc.identifier.epage2724-
dc.identifier.eissn1464-5416-
dc.identifier.isiWOS:000301692700019-
dc.identifier.issnl0040-4020-

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