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Article: Amphiphilic oligo(ethylene glycol)- and poly(ethyleneoxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide)-containing cyclometalated alkynylgold(III) complexes: From basic photophysics to self-assembly and stimuli-responsive properties

TitleAmphiphilic oligo(ethylene glycol)- and poly(ethyleneoxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide)-containing cyclometalated alkynylgold(III) complexes: From basic photophysics to self-assembly and stimuli-responsive properties
Authors
KeywordsAu(III) complexes
Supramolecular chemistry
Luminescence
Metal alkynyls
Issue Date2017
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 2017, v. 845, p. 177-188 How to Cite?
AbstractA class of luminescent cyclometalated gold(III) complexes with oligo(ethylene glycol)- and poly(ethyleneoxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide)-based (PEO-PPO-PEO) alkynyl ligands has been synthesized and characterized. Their photophysical and electrochemical properties have been studied. Cyclometalated gold(III) complexes with oligo(ethylene glycol)-based alkynyl ligands are found to show different aggregation morphologies in DMSO while those with PEO-PPO-PEO-based alkynyl ligand exhibited lower critical solution temperature (LCST) properties in methanol−water (1:1 v/v). Their self-assembly properties have been studied by scanning electron microscopy, transmission electron microscopy, variable-temperature 1H NMR and UV–vis absorption spectroscopy.
Persistent Identifierhttp://hdl.handle.net/10722/243035
ISSN
2019 Impact Factor: 2.304
2015 SCImago Journal Rankings: 0.732
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorSiu, KL-
dc.contributor.authorChung, CYS-
dc.contributor.authorYam, VWW-
dc.date.accessioned2017-08-25T02:49:02Z-
dc.date.available2017-08-25T02:49:02Z-
dc.date.issued2017-
dc.identifier.citationJournal of Organometallic Chemistry, 2017, v. 845, p. 177-188-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/243035-
dc.description.abstractA class of luminescent cyclometalated gold(III) complexes with oligo(ethylene glycol)- and poly(ethyleneoxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide)-based (PEO-PPO-PEO) alkynyl ligands has been synthesized and characterized. Their photophysical and electrochemical properties have been studied. Cyclometalated gold(III) complexes with oligo(ethylene glycol)-based alkynyl ligands are found to show different aggregation morphologies in DMSO while those with PEO-PPO-PEO-based alkynyl ligand exhibited lower critical solution temperature (LCST) properties in methanol−water (1:1 v/v). Their self-assembly properties have been studied by scanning electron microscopy, transmission electron microscopy, variable-temperature 1H NMR and UV–vis absorption spectroscopy.-
dc.languageeng-
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectAu(III) complexes-
dc.subjectSupramolecular chemistry-
dc.subjectLuminescence-
dc.subjectMetal alkynyls-
dc.titleAmphiphilic oligo(ethylene glycol)- and poly(ethyleneoxide)-block-poly(propylene oxide)-block-poly-(ethylene oxide)-containing cyclometalated alkynylgold(III) complexes: From basic photophysics to self-assembly and stimuli-responsive properties-
dc.typeArticle-
dc.identifier.emailSiu, KL: stevenkl@hku.hk-
dc.identifier.emailChung, CYS: cyschung@hku.hk-
dc.identifier.emailYam, VWW: wwyam@hku.hk-
dc.identifier.authorityChung, CYS=rp02672-
dc.identifier.authorityYam, VWW=rp00822-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2017.04.035-
dc.identifier.scopuseid_2-s2.0-85019540224-
dc.identifier.hkuros275301-
dc.identifier.volume845-
dc.identifier.spage177-
dc.identifier.epage188-
dc.identifier.isiWOS:000405773500025-
dc.publisher.placeSwitzerland-
dc.identifier.issnl0022-328X-

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