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Article: Fragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry

TitleFragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry
Authors
KeywordsSulfide complexes
Crystal structure
Electrospray mass spectrometry
Thiolate complexes
Platinum complexes
Metalloligand
Issue Date2008
Citation
Inorganica Chimica Acta, 2008, v. 361, n. 7, p. 1908-1914 How to Cite?
AbstractThe cationic monoalkylated derivatives of the well-known metalloligand [Pt2(μ-S)2(PPh3)4], viz. [Pt2(μ-S)(μ-SR)(PPh3)4]+ (R = n-Bu, CH2Ph) are themselves able to act as metalloligands towards the Ph3PAu+ and R′Hg+ (R′ = Ph or ferrocenyl) fragments, by reaction with Ph3PAuCl or R′HgCl, respectively. The resulting dicationic products [Pt2(μ-SR)(μ-SAuPPh3)(PPh3)4]2+ and [Pt2(μ-SR)(μ-SHgR′)(PPh3)4]2+ are readily isolated as their hexafluorophosphate salts, and have been fully characterised by spectroscopic techniques and an X-ray structure determination on [Pt2(μ-SR)(μ-SHgFc)(PPh3)4](PF6)2. © 2007 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/237580
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorHenderson, William-
dc.contributor.authorNicholson, Brian K.-
dc.contributor.authorDevoy, Sarah M.-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:09:56Z-
dc.date.available2017-01-16T06:09:56Z-
dc.date.issued2008-
dc.identifier.citationInorganica Chimica Acta, 2008, v. 361, n. 7, p. 1908-1914-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/237580-
dc.description.abstractThe cationic monoalkylated derivatives of the well-known metalloligand [Pt2(μ-S)2(PPh3)4], viz. [Pt2(μ-S)(μ-SR)(PPh3)4]+ (R = n-Bu, CH2Ph) are themselves able to act as metalloligands towards the Ph3PAu+ and R′Hg+ (R′ = Ph or ferrocenyl) fragments, by reaction with Ph3PAuCl or R′HgCl, respectively. The resulting dicationic products [Pt2(μ-SR)(μ-SAuPPh3)(PPh3)4]2+ and [Pt2(μ-SR)(μ-SHgR′)(PPh3)4]2+ are readily isolated as their hexafluorophosphate salts, and have been fully characterised by spectroscopic techniques and an X-ray structure determination on [Pt2(μ-SR)(μ-SHgFc)(PPh3)4](PF6)2. © 2007 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganica Chimica Acta-
dc.subjectSulfide complexes-
dc.subjectCrystal structure-
dc.subjectElectrospray mass spectrometry-
dc.subjectThiolate complexes-
dc.subjectPlatinum complexes-
dc.subjectMetalloligand-
dc.titleFragmentation pathways of [Re2(μ-OR)3(CO)6]− (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2007.10.003-
dc.identifier.scopuseid_2-s2.0-41749117075-
dc.identifier.volume361-
dc.identifier.issue7-
dc.identifier.spage1908-
dc.identifier.epage1914-
dc.identifier.isiWOS:000256093500015-

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