File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: [PT2(MU-S)2(PPH3)4] AS A METALLOLIGAND TOWARD MAIN-GROUP LEWIS-ACIDS - THE 1ST SQUARE-PYRAMIDAL STRUCTURE OF AN INDIUM(III) COMPLEX ADDUCT IN (PPH3)4PT2(MU-3-S)2INCL3 AND TETRAHEDRAL GALLIUM(III) IN THE ION-PAIR [(PPH3)4PT2(MU-3-S)2GACL2][GACL4]

Title[PT2(MU-S)2(PPH3)4] AS A METALLOLIGAND TOWARD MAIN-GROUP LEWIS-ACIDS - THE 1ST SQUARE-PYRAMIDAL STRUCTURE OF AN INDIUM(III) COMPLEX ADDUCT IN (PPH3)4PT2(MU-3-S)2INCL3 AND TETRAHEDRAL GALLIUM(III) IN THE ION-PAIR [(PPH3)4PT2(MU-3-S)2GACL2][GACL4]
Authors
Issue Date1994
Citation
Inorganic Chemistry, 1994, v. 33, n. 7, p. 1572-1574 How to Cite?
AbstractLewis acid-base reactions between Pt2(mu-S)2(PPh3)4 (1) and GaCl3 and InCl3 give [(PPh3)4Pt2(mu3-S)2-[GaCl2][GaCl4] (2) and (PPh3)4Pt2(mu3-S)2InCl3 (3), respectively. The cation-anion pair 2 forms as a result of chloride transfer whereas 3 is a 1/1 adduct complex. Compound 3 (illustration) represents the first square-based pyramidal structure of a 5-coordinated adduct of InX3.
Persistent Identifierhttp://hdl.handle.net/10722/237574
ISSN
2017 Impact Factor: 4.7
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorZhou, Meisheng-
dc.contributor.authorXu, Yan-
dc.contributor.authorLam, Choon Fui-
dc.contributor.authorLeung, Pak Hing-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorMok, K. F.-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:09:53Z-
dc.date.available2017-01-16T06:09:53Z-
dc.date.issued1994-
dc.identifier.citationInorganic Chemistry, 1994, v. 33, n. 7, p. 1572-1574-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/237574-
dc.description.abstractLewis acid-base reactions between Pt2(mu-S)2(PPh3)4 (1) and GaCl3 and InCl3 give [(PPh3)4Pt2(mu3-S)2-[GaCl2][GaCl4] (2) and (PPh3)4Pt2(mu3-S)2InCl3 (3), respectively. The cation-anion pair 2 forms as a result of chloride transfer whereas 3 is a 1/1 adduct complex. Compound 3 (illustration) represents the first square-based pyramidal structure of a 5-coordinated adduct of InX3.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.title[PT2(MU-S)2(PPH3)4] AS A METALLOLIGAND TOWARD MAIN-GROUP LEWIS-ACIDS - THE 1ST SQUARE-PYRAMIDAL STRUCTURE OF AN INDIUM(III) COMPLEX ADDUCT IN (PPH3)4PT2(MU-3-S)2INCL3 AND TETRAHEDRAL GALLIUM(III) IN THE ION-PAIR [(PPH3)4PT2(MU-3-S)2GACL2][GACL4]-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic00085a060-
dc.identifier.scopuseid_2-s2.0-33751157753-
dc.identifier.volume33-
dc.identifier.issue7-
dc.identifier.spage1572-
dc.identifier.epage1574-
dc.identifier.isiWOS:A1994NE10200060-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats