File Download
There are no files associated with this item.
Links for fulltext
(May Require Subscription)
- Publisher Website: 10.1039/c4qi00081a
- Scopus: eid_2-s2.0-84946840397
- WOS: WOS:000364543000007
- Find via
Supplementary
- Citations:
- Appears in Collections:
Article: A biomimetic photoelectrochemical device from a molecular heterometallic sodium-manganese water splitting catalyst
| Title | A biomimetic photoelectrochemical device from a molecular heterometallic sodium-manganese water splitting catalyst |
|---|---|
| Authors | |
| Issue Date | 2014 |
| Citation | Inorganic Chemistry Frontiers, 2014, v. 1, n. 9, p. 705-711 How to Cite? |
| Abstract | © the Partner Organisations 2014.A photoelectrochemical device for water splitting has been fabricated from a new water stable molecular [Na2Mn4] complex that acts as an in situ precursor towards NaMn2Ox nanoparticles under catalytic conditions when immobilized within a conductive PEDOT:PSS/Nafion composite film for optimal electron transport. The optimized photoanode architecture of ITO/TiO2/Ru/60% PEDOT:PSS/Na2Mn4/Nafion resulted in a water oxidation onset potential of 1.35 V (vs. RHE) and achieved a maximum current density of 1.31 mA cm-2 (initial) and 0.80 mA cm-2 (stabilized) at 1.8 V (vs. RHE) at pH 6.5. |
| Persistent Identifier | http://hdl.handle.net/10722/237514 |
| ISSN | 2020 SCImago Journal Rankings: 1.421 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Gan, C. R Raymond | - |
| dc.contributor.author | Liu, Zhaolin | - |
| dc.contributor.author | Bai, Shi Qiang | - |
| dc.contributor.author | Tay, Siok Wei | - |
| dc.contributor.author | Ge, Xiaoming | - |
| dc.contributor.author | Wu, Ji En | - |
| dc.contributor.author | Hor, T. S Andy | - |
| dc.date.accessioned | 2017-01-16T06:09:21Z | - |
| dc.date.available | 2017-01-16T06:09:21Z | - |
| dc.date.issued | 2014 | - |
| dc.identifier.citation | Inorganic Chemistry Frontiers, 2014, v. 1, n. 9, p. 705-711 | - |
| dc.identifier.issn | 2052-1545 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/237514 | - |
| dc.description.abstract | © the Partner Organisations 2014.A photoelectrochemical device for water splitting has been fabricated from a new water stable molecular [Na2Mn4] complex that acts as an in situ precursor towards NaMn2Ox nanoparticles under catalytic conditions when immobilized within a conductive PEDOT:PSS/Nafion composite film for optimal electron transport. The optimized photoanode architecture of ITO/TiO2/Ru/60% PEDOT:PSS/Na2Mn4/Nafion resulted in a water oxidation onset potential of 1.35 V (vs. RHE) and achieved a maximum current density of 1.31 mA cm-2 (initial) and 0.80 mA cm-2 (stabilized) at 1.8 V (vs. RHE) at pH 6.5. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Inorganic Chemistry Frontiers | - |
| dc.title | A biomimetic photoelectrochemical device from a molecular heterometallic sodium-manganese water splitting catalyst | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/c4qi00081a | - |
| dc.identifier.scopus | eid_2-s2.0-84946840397 | - |
| dc.identifier.volume | 1 | - |
| dc.identifier.issue | 9 | - |
| dc.identifier.spage | 705 | - |
| dc.identifier.epage | 711 | - |
| dc.identifier.eissn | 2052-1553 | - |
| dc.identifier.isi | WOS:000364543000007 | - |
| dc.identifier.issnl | 2052-1545 | - |