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Article: Chromatography-Free Esterification Reactions Using a Bifunctional Polymer

TitleChromatography-Free Esterification Reactions Using a Bifunctional Polymer
Authors
Issue Date2016
PublisherGeorg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml
Citation
Synlett, 2016, v. 27 n. 08, p. 1207-1210 How to Cite?
AbstractA linear polystyrene functionalized with both nucleophilic DMAP groups and sterically hindered tertiary amine groups was synthesized and used homogeneously in a range of esterification reactions between alcohols and various carboxylic acid derivatives. The polymer was highly effective in such reactions where the DMAP groups served as catalytic groups. The ester products of these reactions could be isolated in high purity and yield without the need for chromatographic purification, and the polymer could be recovered and reused numerous times with no apparent decrease in utility.
Persistent Identifierhttp://hdl.handle.net/10722/234028
ISSN
2015 Impact Factor: 2.323
2015 SCImago Journal Rankings: 0.908

 

DC FieldValueLanguage
dc.contributor.authorMa, S-
dc.contributor.authorToy, PH-
dc.date.accessioned2016-10-14T06:58:34Z-
dc.date.available2016-10-14T06:58:34Z-
dc.date.issued2016-
dc.identifier.citationSynlett, 2016, v. 27 n. 08, p. 1207-1210-
dc.identifier.issn0936-5214-
dc.identifier.urihttp://hdl.handle.net/10722/234028-
dc.description.abstractA linear polystyrene functionalized with both nucleophilic DMAP groups and sterically hindered tertiary amine groups was synthesized and used homogeneously in a range of esterification reactions between alcohols and various carboxylic acid derivatives. The polymer was highly effective in such reactions where the DMAP groups served as catalytic groups. The ester products of these reactions could be isolated in high purity and yield without the need for chromatographic purification, and the polymer could be recovered and reused numerous times with no apparent decrease in utility.-
dc.languageeng-
dc.publisherGeorg Thieme Verlag. The Journal's web site is located at http://www.thieme-chemistry.com/thieme-chemistry/journals/info/synlett/index.shtml-
dc.relation.ispartofSynlett-
dc.rightsSynlett. Copyright © Georg Thieme Verlag.-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.titleChromatography-Free Esterification Reactions Using a Bifunctional Polymer-
dc.typeArticle-
dc.identifier.emailToy, PH: phtoy@hkucc.hku.hk-
dc.identifier.authorityToy, PH=rp00791-
dc.description.naturepostprint-
dc.identifier.doi10.1055/s-0035-1560415-
dc.identifier.hkuros267609-
dc.identifier.volume27-
dc.identifier.issue08-
dc.identifier.spage1207-
dc.identifier.epage1210-
dc.publisher.placeGermany-

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