File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Thermal Regulation of Colloidal Materials Architecture through Orthogonal Functionalizable Patchy Particles

TitleThermal Regulation of Colloidal Materials Architecture through Orthogonal Functionalizable Patchy Particles
Authors
Issue Date2016
Citation
Chemistry of Materials, 2016, v. 28, n. 11, p. 3984-3989 How to Cite?
Abstract© 2016 American Chemical Society.This contribution presents a sol-gel based cluster encapsulation methodology to produce bifunctional patchy particles. The particles possess azide moieties on the surfaces of the patch and carboxylic acids on the shell. Two types of DNA with distinct terminal sequences are site-specifically conjugated to the particle patches or the shell employing two orthogonal coupling strategies: strain-promoted alkyne-azide cycloaddition and carbodiimide-mediated amidation. We can activate and deactivate assembly on the patches and/or the shell through thermal control, demonstrating reversible and stepwise self-assembly.
Persistent Identifierhttp://hdl.handle.net/10722/230634
ISSN
2015 Impact Factor: 9.407
2015 SCImago Journal Rankings: 4.232

 

DC FieldValueLanguage
dc.contributor.authorWang, Yu-
dc.contributor.authorZheng, Xiaolong-
dc.contributor.authorWang, Yufeng-
dc.contributor.authorPine, David J.-
dc.contributor.authorWeck, Marcus-
dc.date.accessioned2016-09-01T06:06:25Z-
dc.date.available2016-09-01T06:06:25Z-
dc.date.issued2016-
dc.identifier.citationChemistry of Materials, 2016, v. 28, n. 11, p. 3984-3989-
dc.identifier.issn0897-4756-
dc.identifier.urihttp://hdl.handle.net/10722/230634-
dc.description.abstract© 2016 American Chemical Society.This contribution presents a sol-gel based cluster encapsulation methodology to produce bifunctional patchy particles. The particles possess azide moieties on the surfaces of the patch and carboxylic acids on the shell. Two types of DNA with distinct terminal sequences are site-specifically conjugated to the particle patches or the shell employing two orthogonal coupling strategies: strain-promoted alkyne-azide cycloaddition and carbodiimide-mediated amidation. We can activate and deactivate assembly on the patches and/or the shell through thermal control, demonstrating reversible and stepwise self-assembly.-
dc.languageeng-
dc.relation.ispartofChemistry of Materials-
dc.titleThermal Regulation of Colloidal Materials Architecture through Orthogonal Functionalizable Patchy Particles-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/acs.chemmater.6b01313-
dc.identifier.scopuseid_2-s2.0-84975076504-
dc.identifier.volume28-
dc.identifier.issue11-
dc.identifier.spage3984-
dc.identifier.epage3989-
dc.identifier.eissn1520-5002-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats