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Article: Discoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(I) or copper(II) template?

TitleDiscoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(I) or copper(II) template?
Authors
Issue Date2016
PublisherRSC Publications. The Journal's web site is located at http://www.rsc.org/publishing/journals/qi/about.asp
Citation
Inorganic Chemistry Frontiers, 2016, v. 3 n. 3, p. 348-353 How to Cite?
AbstractWe report here a DCL study of a phenanthroline-based building block focusing on catenane formation with copper templates. Two [2]catenanes have been amplified by using Cu+ as a template from the DCLs that contain no interlocked compounds in the absence of copper. In addition, an unexpected Cu2+ template effect on the [2]catenane formation was discovered. The observed Cu2+ template effect was found to originate from the in situ reduction of the divalent metal to Cu+.
Persistent Identifierhttp://hdl.handle.net/10722/226306
ISSN
2015 Impact Factor: 4.532
2015 SCImago Journal Rankings: 1.514

 

DC FieldValueLanguage
dc.contributor.authorTong, KL-
dc.contributor.authorYee, CC-
dc.contributor.authorTse, YC-
dc.contributor.authorAu Yeung, HY-
dc.date.accessioned2016-06-17T07:43:12Z-
dc.date.available2016-06-17T07:43:12Z-
dc.date.issued2016-
dc.identifier.citationInorganic Chemistry Frontiers, 2016, v. 3 n. 3, p. 348-353-
dc.identifier.issn2052-1553-
dc.identifier.urihttp://hdl.handle.net/10722/226306-
dc.description.abstractWe report here a DCL study of a phenanthroline-based building block focusing on catenane formation with copper templates. Two [2]catenanes have been amplified by using Cu+ as a template from the DCLs that contain no interlocked compounds in the absence of copper. In addition, an unexpected Cu2+ template effect on the [2]catenane formation was discovered. The observed Cu2+ template effect was found to originate from the in situ reduction of the divalent metal to Cu+.-
dc.languageeng-
dc.publisherRSC Publications. The Journal's web site is located at http://www.rsc.org/publishing/journals/qi/about.asp-
dc.relation.ispartofInorganic Chemistry Frontiers-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.titleDiscoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(I) or copper(II) template?-
dc.typeArticle-
dc.identifier.emailAu Yeung, HY: hoyuay@hku.hk-
dc.identifier.authorityAu Yeung, HY=rp01819-
dc.description.naturepostprint-
dc.identifier.doi10.1039/C5QI00227C-
dc.identifier.hkuros258678-
dc.identifier.volume3-
dc.identifier.issue3-
dc.identifier.spage348-
dc.identifier.epage353-
dc.publisher.placeUnited Kingdom-

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