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Article: Metal-organic framework threaded with aminated polymer formed in situ for fast and reversible ion exchange

TitleMetal-organic framework threaded with aminated polymer formed in situ for fast and reversible ion exchange
Authors
Issue Date2014
Citation
Journal of the American Chemical Society, 2014, v. 136, n. 20, p. 7209-7212 How to Cite?
AbstractA porous metal-organic framework composite with flexible anion-exchange polymers threaded within the host cavity demonstrates very fast and reversible ion-exchange activity. Polyvinyl benzyl trimethylammonium hydroxide (PVBTAH) caged in ZIF-8 is synthesized in steps of chloro-monomer impregnation, in situ polymerization, amination, and alkaline ion exchange. The synthesized non-cross-linked PVBTAH∼ZIF-8 material exhibits superior ion-exchange kinetics compared to conventional ion-exchange resins. © 2014 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/222671
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorGao, Liang-
dc.contributor.authorLi, Chi Ying Vanessa-
dc.contributor.authorChan, Kwong Yu-
dc.contributor.authorChen, Zhe Ning-
dc.date.accessioned2016-01-19T03:36:54Z-
dc.date.available2016-01-19T03:36:54Z-
dc.date.issued2014-
dc.identifier.citationJournal of the American Chemical Society, 2014, v. 136, n. 20, p. 7209-7212-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/222671-
dc.description.abstractA porous metal-organic framework composite with flexible anion-exchange polymers threaded within the host cavity demonstrates very fast and reversible ion-exchange activity. Polyvinyl benzyl trimethylammonium hydroxide (PVBTAH) caged in ZIF-8 is synthesized in steps of chloro-monomer impregnation, in situ polymerization, amination, and alkaline ion exchange. The synthesized non-cross-linked PVBTAH∼ZIF-8 material exhibits superior ion-exchange kinetics compared to conventional ion-exchange resins. © 2014 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleMetal-organic framework threaded with aminated polymer formed in situ for fast and reversible ion exchange-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja501958u-
dc.identifier.pmid24802277-
dc.identifier.scopuseid_2-s2.0-84900988108-
dc.identifier.hkuros231460-
dc.identifier.volume136-
dc.identifier.issue20-
dc.identifier.spage7209-
dc.identifier.epage7212-
dc.identifier.eissn1520-5126-
dc.identifier.isiWOS:000336416600006-

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