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Article: Coordination chemistry of the metalloligand [Pt2(μ-S) 2(PPh3)4] with nickel(II) complexes - An electrospray mass spectrometry directed synthetic study

TitleCoordination chemistry of the metalloligand [Pt2(μ-S) 2(PPh3)4] with nickel(II) complexes - An electrospray mass spectrometry directed synthetic study
Authors
KeywordsElectrospray mass spectrometry
Mixed-metal complexes
Nickel complexes
Sulfide ligands
Platinum complexes
Issue Date2004
Citation
Inorganica Chimica Acta, 2004, v. 357, n. 4, p. 1152-1160 How to Cite?
AbstractThe reactivity of [Pt2(μ-S)2(PPh3) 4] towards a range of nickel(II) complexes has been probed using electrospray ionisation mass spectrometry coupled with synthesis and characterisation in selected systems. Reaction of [Pt2(μ-S) 2(PPh3)4] with [Ni(NCS)2(PPh 3)2] gives [Pt2(μ-S)2(PPh 3)4Ni(NCS)(PPh3)]+, isolated as its BPh4 - salt; the same product is obtained in the reaction of [Pt2(μ-S)2(PPh3)4] with [NiBr2(PPh3)2] and KNCS. An X-ray structure determination reveals the expected sulfide-bridged structure, with an N-bonded thiocyanate ligand and a square-planar coordination geometry about nickel. A range of nickel(II) complexes NiL2, containing β-diketonate, 8-hydroxyquinolinate, or salicylaldehyde oximate ligands react similarly, giving [Pt2(μ-S)2(PPh3)4NiL] + cations. © 2003 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219840
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584

 

DC FieldValueLanguage
dc.contributor.authorFong, S. W Audi-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorVittal, Jagadese J.-
dc.contributor.authorHenderson, William-
dc.contributor.authorCramp, Shelley-
dc.date.accessioned2015-09-23T02:58:04Z-
dc.date.available2015-09-23T02:58:04Z-
dc.date.issued2004-
dc.identifier.citationInorganica Chimica Acta, 2004, v. 357, n. 4, p. 1152-1160-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/219840-
dc.description.abstractThe reactivity of [Pt2(μ-S)2(PPh3) 4] towards a range of nickel(II) complexes has been probed using electrospray ionisation mass spectrometry coupled with synthesis and characterisation in selected systems. Reaction of [Pt2(μ-S) 2(PPh3)4] with [Ni(NCS)2(PPh 3)2] gives [Pt2(μ-S)2(PPh 3)4Ni(NCS)(PPh3)]+, isolated as its BPh4 - salt; the same product is obtained in the reaction of [Pt2(μ-S)2(PPh3)4] with [NiBr2(PPh3)2] and KNCS. An X-ray structure determination reveals the expected sulfide-bridged structure, with an N-bonded thiocyanate ligand and a square-planar coordination geometry about nickel. A range of nickel(II) complexes NiL2, containing β-diketonate, 8-hydroxyquinolinate, or salicylaldehyde oximate ligands react similarly, giving [Pt2(μ-S)2(PPh3)4NiL] + cations. © 2003 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganica Chimica Acta-
dc.subjectElectrospray mass spectrometry-
dc.subjectMixed-metal complexes-
dc.subjectNickel complexes-
dc.subjectSulfide ligands-
dc.subjectPlatinum complexes-
dc.titleCoordination chemistry of the metalloligand [Pt2(μ-S) 2(PPh3)4] with nickel(II) complexes - An electrospray mass spectrometry directed synthetic study-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2003.03.002-
dc.identifier.scopuseid_2-s2.0-1542286591-
dc.identifier.volume357-
dc.identifier.issue4-
dc.identifier.spage1152-
dc.identifier.epage1160-

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