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Article: Copper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation

TitleCopper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation
Authors
Issue Date2014
Citation
Organic Letters, 2014, v. 16, n. 2, p. 524-527 How to Cite?
AbstractA catalytic trifluoromethylselenolation of aryl and alkyl halides by a Cu(I) catalyst has been developed. A key intermediate, [(phen)Cu(SeCF3)]2 (5) was successfully isolated and characterized by X-ray diffraction. The important role of silver in the transmetalation process during the catalytic cycle was elucidated. A wide range of trifluoromethylselanes have been prepared from readily available starting materials from a method that tolerates various important functional groups. © 2013 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/219744
ISSN
2015 Impact Factor: 6.732
2015 SCImago Journal Rankings: 3.187

 

DC FieldValueLanguage
dc.contributor.authorChen, Chaohuang-
dc.contributor.authorHou, Chuanqi-
dc.contributor.authorWang, Yuguang-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorWeng, Zhiqiang-
dc.date.accessioned2015-09-23T02:57:52Z-
dc.date.available2015-09-23T02:57:52Z-
dc.date.issued2014-
dc.identifier.citationOrganic Letters, 2014, v. 16, n. 2, p. 524-527-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10722/219744-
dc.description.abstractA catalytic trifluoromethylselenolation of aryl and alkyl halides by a Cu(I) catalyst has been developed. A key intermediate, [(phen)Cu(SeCF3)]2 (5) was successfully isolated and characterized by X-ray diffraction. The important role of silver in the transmetalation process during the catalytic cycle was elucidated. A wide range of trifluoromethylselanes have been prepared from readily available starting materials from a method that tolerates various important functional groups. © 2013 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofOrganic Letters-
dc.titleCopper-catalyzed trifluoromethylselenolation of aryl and alkyl halides: The silver effect in transmetalation-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ol403406y-
dc.identifier.scopuseid_2-s2.0-84896749154-
dc.identifier.volume16-
dc.identifier.issue2-
dc.identifier.spage524-
dc.identifier.epage527-
dc.identifier.eissn1523-7052-

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