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Article: Probing the origin of in situ generated nanoparticles as sustainable oxidation catalysts

TitleProbing the origin of in situ generated nanoparticles as sustainable oxidation catalysts
Authors
Issue Date2013
Citation
Dalton Transactions, 2013, v. 42, n. 35, p. 12600-12605 How to Cite?
AbstractA novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure-property correlations. © 2013 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219712
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorHinde, Christopher S.-
dc.contributor.authorVan Aswegen, Sivan-
dc.contributor.authorCollins, Gillian-
dc.contributor.authorHolmes, Justin D.-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorRaja, Robert-
dc.date.accessioned2015-09-23T02:57:47Z-
dc.date.available2015-09-23T02:57:47Z-
dc.date.issued2013-
dc.identifier.citationDalton Transactions, 2013, v. 42, n. 35, p. 12600-12605-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219712-
dc.description.abstractA novel method for the in situ generation of catalytically active small metal nanoparticles, by anion extrusion on a parent porous copper chloropyrophosphate framework, has been developed to generate gold, platinum and palladium nanoparticles for sustainable catalytic oxidations using molecular oxygen as the oxidant. Transmission electron microscopy coupled with detailed structural and physico-chemical characterisation, in combination with in-depth kinetic analysis have afforded profound insights into the nature of the active site for facilitating structure-property correlations. © 2013 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleProbing the origin of in situ generated nanoparticles as sustainable oxidation catalysts-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c3dt50606a-
dc.identifier.pmid23698390-
dc.identifier.scopuseid_2-s2.0-84882260173-
dc.identifier.volume42-
dc.identifier.issue35-
dc.identifier.spage12600-
dc.identifier.epage12605-
dc.identifier.eissn1477-9234-

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