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Article: Hybrid NS ligands supported Cu(i)/(ii) complexes for azide-alkyne cycloaddition reactions

TitleHybrid NS ligands supported Cu(i)/(ii) complexes for azide-alkyne cycloaddition reactions
Authors
Issue Date2013
Citation
Dalton Transactions, 2013, v. 42, n. 31, p. 11319-11326 How to Cite?
AbstractThree copper complexes of nitrogen-sulfur donor ligands, [CuBr 2(L1)] (1), [CuCl2(L2)2] (2) and [Cu 2I2(L3)]n (3) (L1 = bis(2- cyclohexylsulfanylethyl)amine, L2 = 2-(benzylsulfanylmethyl)pyridine and L3 = 2-(4-pyridylsulfanylmethyl)pyridine), have been synthesized and characterized by single-crystal X-ray diffraction (XRD), powder XRD and TGA analysis. Complexes 1 and 2 are mononuclear Cu(ii) complexes and are EPR active with distorted square-pyramidal and octahedral geometry, respectively. Complex 3 is a two-dimensional tetrahedral Cu(i) coordination polymer with 16- and 20-membered metallocycles. These complexes show good catalytic activities for one-pot azide-alkyne cycloaddition reactions in CH3OH-H2O. © 2013 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219707
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorBai, Shi Qiang-
dc.contributor.authorJiang, Lu-
dc.contributor.authorZuo, Jing Lin-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:46Z-
dc.date.available2015-09-23T02:57:46Z-
dc.date.issued2013-
dc.identifier.citationDalton Transactions, 2013, v. 42, n. 31, p. 11319-11326-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219707-
dc.description.abstractThree copper complexes of nitrogen-sulfur donor ligands, [CuBr 2(L1)] (1), [CuCl2(L2)2] (2) and [Cu 2I2(L3)]n (3) (L1 = bis(2- cyclohexylsulfanylethyl)amine, L2 = 2-(benzylsulfanylmethyl)pyridine and L3 = 2-(4-pyridylsulfanylmethyl)pyridine), have been synthesized and characterized by single-crystal X-ray diffraction (XRD), powder XRD and TGA analysis. Complexes 1 and 2 are mononuclear Cu(ii) complexes and are EPR active with distorted square-pyramidal and octahedral geometry, respectively. Complex 3 is a two-dimensional tetrahedral Cu(i) coordination polymer with 16- and 20-membered metallocycles. These complexes show good catalytic activities for one-pot azide-alkyne cycloaddition reactions in CH3OH-H2O. © 2013 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleHybrid NS ligands supported Cu(i)/(ii) complexes for azide-alkyne cycloaddition reactions-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c3dt50247c-
dc.identifier.scopuseid_2-s2.0-84880636842-
dc.identifier.volume42-
dc.identifier.issue31-
dc.identifier.spage11319-
dc.identifier.epage11326-
dc.identifier.eissn1477-9234-

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