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Article: Cp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer

TitleCp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer
Authors
Issue Date2013
Citation
Journal of the American Chemical Society, 2013, v. 135, n. 22, p. 8125-8128 How to Cite?
AbstractA series of CpRh-based functional metallarectangles have been synthesized from metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link architectures. All these complexes are intact in solution, as evident from ESI-MS spectroscopic analysis. Arising from the combination of open Cu centers and favorable cavity space, {(CpRh)4(bpe) 2[Cu(opba)·2MeOH]2}4(OTf)·6MeOH shows extraordinary catalytic abilities with high efficiency and wide substrate selectivity in the acyl-transfer reaction. © 2013 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/219703
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123

 

DC FieldValueLanguage
dc.contributor.authorHuang, Sheng Li-
dc.contributor.authorLin, Yue Jian-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorJin, Guo Xin-
dc.date.accessioned2015-09-23T02:57:46Z-
dc.date.available2015-09-23T02:57:46Z-
dc.date.issued2013-
dc.identifier.citationJournal of the American Chemical Society, 2013, v. 135, n. 22, p. 8125-8128-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/219703-
dc.description.abstractA series of CpRh-based functional metallarectangles have been synthesized from metallaligands. Enlargement of one linker leads to the isolation of two novel Borromean link architectures. All these complexes are intact in solution, as evident from ESI-MS spectroscopic analysis. Arising from the combination of open Cu centers and favorable cavity space, {(CpRh)4(bpe) 2[Cu(opba)·2MeOH]2}4(OTf)·6MeOH shows extraordinary catalytic abilities with high efficiency and wide substrate selectivity in the acyl-transfer reaction. © 2013 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleCp*Rh-based heterometallic metallarectangles: Size-dependent borromean link structures and catalytic acyl transfer-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja402630g-
dc.identifier.pmid23678944-
dc.identifier.scopuseid_2-s2.0-84878660750-
dc.identifier.volume135-
dc.identifier.issue22-
dc.identifier.spage8125-
dc.identifier.epage8128-
dc.identifier.eissn1520-5126-

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