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Article: General one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates

TitleGeneral one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates
Authors
Issue Date2012
Citation
Inorganic Chemistry, 2012, v. 51, n. 22, p. 12059-12061 How to Cite?
AbstractA new family of Co/rare-earth intermetallic cubane aggregates [Co 3Ln(hmp) 4(OAc) 5H 2O] (Ln = Dy, Ho, Er, Tm, Yb, Y) have been synthesized by self-assembly. Single-crystal X-ray diffraction analysis revealed that they are remarkably isostructural in showing a common [Co 3Ln] core. Magnetic studies showed that the Dy, Er, Tm, Yb, and Y complexes are ferromagnetic. The Dy complex exhibits the largest magnetocaloric effect (-ΔS m = 12.58 J kg -1 K -1), which can be attributed to the large magnetic density of Dy III. © 2012 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/219680
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873

 

DC FieldValueLanguage
dc.contributor.authorWang, Pei-
dc.contributor.authorShannigrahi, Santiranjan-
dc.contributor.authorYakovlev, Nikolai L.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:42Z-
dc.date.available2015-09-23T02:57:42Z-
dc.date.issued2012-
dc.identifier.citationInorganic Chemistry, 2012, v. 51, n. 22, p. 12059-12061-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/219680-
dc.description.abstractA new family of Co/rare-earth intermetallic cubane aggregates [Co 3Ln(hmp) 4(OAc) 5H 2O] (Ln = Dy, Ho, Er, Tm, Yb, Y) have been synthesized by self-assembly. Single-crystal X-ray diffraction analysis revealed that they are remarkably isostructural in showing a common [Co 3Ln] core. Magnetic studies showed that the Dy, Er, Tm, Yb, and Y complexes are ferromagnetic. The Dy complex exhibits the largest magnetocaloric effect (-ΔS m = 12.58 J kg -1 K -1), which can be attributed to the large magnetic density of Dy III. © 2012 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleGeneral one-step self-assembly of isostructural intermetallic Co II 3Ln III Cubane Aggregates-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic301527b-
dc.identifier.scopuseid_2-s2.0-84869443870-
dc.identifier.volume51-
dc.identifier.issue22-
dc.identifier.spage12059-
dc.identifier.epage12061-

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