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Article: Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)

TitleFunctionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)
Authors
Issue Date2010
Citation
Dalton Transactions, 2010, v. 39, n. 10, p. 2631-2636 How to Cite?
AbstractTwo 3-D and one 2-D metal-organic frameworks [Cu8I 8(L1)4]n (1), [Cu8I 8(L2)4]n (2) and [Cu4I 4(L3)2]n (3) were synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles, 1-(4-picolyl)-4-butyl-1H-1,2, 3-triazole (L1), 1-(4-picolyl)-4-pentyl-1H-1,2,3-triazole (L2) and 1-(4-picolyl)-4-(3,5-dimethylpyrazolylmethyl)-1H-1,2,3-triazole (L3). In both complexes 1 and 2, there co-exist a 1-D Cu(i) oligomer and Cu4 tetrahedron cluster in the 3-D polymeric structures. Complex 3 shows a 2-D (4, 4) net with the stair-step Cu4I4 as node and L3 as a building block. All three complexes exhibit photoluminescence. © The Royal Society of Chemistry 2010.
Persistent Identifierhttp://hdl.handle.net/10722/219622
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorBai, Shi Qiang-
dc.contributor.authorKwang, Jia Yi-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorYoung, David J.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:33Z-
dc.date.available2015-09-23T02:57:33Z-
dc.date.issued2010-
dc.identifier.citationDalton Transactions, 2010, v. 39, n. 10, p. 2631-2636-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219622-
dc.description.abstractTwo 3-D and one 2-D metal-organic frameworks [Cu8I 8(L1)4]n (1), [Cu8I 8(L2)4]n (2) and [Cu4I 4(L3)2]n (3) were synthesized using three novel pyridine and pyrazole supported 1,2,3-triazoles, 1-(4-picolyl)-4-butyl-1H-1,2, 3-triazole (L1), 1-(4-picolyl)-4-pentyl-1H-1,2,3-triazole (L2) and 1-(4-picolyl)-4-(3,5-dimethylpyrazolylmethyl)-1H-1,2,3-triazole (L3). In both complexes 1 and 2, there co-exist a 1-D Cu(i) oligomer and Cu4 tetrahedron cluster in the 3-D polymeric structures. Complex 3 shows a 2-D (4, 4) net with the stair-step Cu4I4 as node and L3 as a building block. All three complexes exhibit photoluminescence. © The Royal Society of Chemistry 2010.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleFunctionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(i)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b918223c-
dc.identifier.pmid20179857-
dc.identifier.scopuseid_2-s2.0-77249128960-
dc.identifier.volume39-
dc.identifier.issue10-
dc.identifier.spage2631-
dc.identifier.epage2636-
dc.identifier.eissn1477-9234-

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