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Article: Benzothiazolin-2-ylidene and azole mixed-ligand complexes of palladium

TitleBenzothiazolin-2-ylidene and azole mixed-ligand complexes of palladium
Authors
KeywordsNitrogen heterocycles
Carbene ligands
Cross-coupling
N, S ligands
Palladium
Issue Date2009
Citation
European Journal of Inorganic Chemistry, 2009, n. 28, p. 4288-4297 How to Cite?
AbstractA series of mixed-ligand, mononuclear complexes trans[PdX 2(NSHC)(azole)] [NSHC = N,S-heterocyclic carbene; azole = imidazole, l-(2,4,6-trimethylphenyl)-1H-imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X-ray single-crystal diffrac-tion. These complexes catalyse the sp2-sp3 cross-coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers, © Wiley-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/219608
ISSN
2015 Impact Factor: 2.686
2015 SCImago Journal Rankings: 1.018

 

DC FieldValueLanguage
dc.contributor.authorYen, Swee Kuan-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHuynh, Han Vinh-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:31Z-
dc.date.available2015-09-23T02:57:31Z-
dc.date.issued2009-
dc.identifier.citationEuropean Journal of Inorganic Chemistry, 2009, n. 28, p. 4288-4297-
dc.identifier.issn1434-1948-
dc.identifier.urihttp://hdl.handle.net/10722/219608-
dc.description.abstractA series of mixed-ligand, mononuclear complexes trans[PdX 2(NSHC)(azole)] [NSHC = N,S-heterocyclic carbene; azole = imidazole, l-(2,4,6-trimethylphenyl)-1H-imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X-ray single-crystal diffrac-tion. These complexes catalyse the sp2-sp3 cross-coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers, © Wiley-VCH Verlag GmbH & Co. KGaA.-
dc.languageeng-
dc.relation.ispartofEuropean Journal of Inorganic Chemistry-
dc.subjectNitrogen heterocycles-
dc.subjectCarbene ligands-
dc.subjectCross-coupling-
dc.subjectN, S ligands-
dc.subjectPalladium-
dc.titleBenzothiazolin-2-ylidene and azole mixed-ligand complexes of palladium-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/ejic.200900447-
dc.identifier.scopuseid_2-s2.0-70349305515-
dc.identifier.issue28-
dc.identifier.spage4288-
dc.identifier.epage4297-
dc.identifier.eissn1099-0682-

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