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Article: Solid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates

TitleSolid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates
Authors
Issue Date1990
Citation
Thermochimica Acta, 1990, v. 167, n. 1, p. 57-64 How to Cite?
AbstractThe solid state decomposition of Ni(CN)2(NH3)(G)n (or strictly, Ni(NH3)2Ni(CN)4· 2nG) where G = aniline, benzene and phenol, has been monitored by infrared spectroscopy, and thermogravimetric (TG) and differential scanning calorimetric analyses. The inclusion ratio, n, which can be conveniently obtained from the thermal profiles, follows the order C6H5NH2 /s C6H5OH /s C6H6. The step-wise degradation of these clathrates has been followed by TG and modelling experiments in Schlenk flasks. All the decompositional intermediates have been isolated and identified by TG, IR and microanalyses. © 1990.
Persistent Identifierhttp://hdl.handle.net/10722/219574
ISSN
2015 Impact Factor: 1.938
2015 SCImago Journal Rankings: 0.708

 

DC FieldValueLanguage
dc.contributor.authorHor, T. S A-
dc.contributor.authorChan, H. S O-
dc.contributor.authorLee, H. K.-
dc.contributor.authorDoshi, S. D.-
dc.contributor.authorLeong, Y. P.-
dc.contributor.authorLian, W. T.-
dc.contributor.authorPhang, L. T.-
dc.contributor.authorSim, M. M.-
dc.contributor.authorTan, M. M.-
dc.date.accessioned2015-09-23T02:57:26Z-
dc.date.available2015-09-23T02:57:26Z-
dc.date.issued1990-
dc.identifier.citationThermochimica Acta, 1990, v. 167, n. 1, p. 57-64-
dc.identifier.issn0040-6031-
dc.identifier.urihttp://hdl.handle.net/10722/219574-
dc.description.abstractThe solid state decomposition of Ni(CN)2(NH3)(G)n (or strictly, Ni(NH3)2Ni(CN)4· 2nG) where G = aniline, benzene and phenol, has been monitored by infrared spectroscopy, and thermogravimetric (TG) and differential scanning calorimetric analyses. The inclusion ratio, n, which can be conveniently obtained from the thermal profiles, follows the order C6H5NH2 /s C6H5OH /s C6H6. The step-wise degradation of these clathrates has been followed by TG and modelling experiments in Schlenk flasks. All the decompositional intermediates have been isolated and identified by TG, IR and microanalyses. © 1990.-
dc.languageeng-
dc.relation.ispartofThermochimica Acta-
dc.titleSolid-state thermolysis of trans-diamminenickel(ii) catena-tetra-μ-cyanonickelate(II)clathrates and their degradation intermediates-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0040-6031(90)80464-A-
dc.identifier.scopuseid_2-s2.0-44949290898-
dc.identifier.volume167-
dc.identifier.issue1-
dc.identifier.spage57-
dc.identifier.epage64-

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