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Article: PdCl[PPh 2CH 2CH 2CHCH 2CH 2PPh 2] as a precursor to homo-and hetero-metallic species directed by ESMS (electrospray ionisation mass spectrometry)

TitlePdCl[PPh 2CH 2CH 2CHCH 2CH 2PPh 2] as a precursor to homo-and hetero-metallic species directed by ESMS (electrospray ionisation mass spectrometry)
Authors
Issue Date2004
Citation
Dalton Transactions, 2004, n. 15, p. 2281-2287 How to Cite?
AbstractThe cyclometallated Pd compound PdCl[PPh 2CH 2CH 2CHCH 2CH 2PPh 2] 1, obtained from PdCl 2Ph 2P(CH 2) 5PPh 2) in refluxing DMF (N,N-dimethylformamide), was characterized by NMR and X-ray single-crystal diffraction analysis. The cyclometallation of MCl 2(Ph 2P(CH 2) 5PPh 2) (M = Pd, Pt) to give 1 and its Pt(II) analogue was probed using electrospray ionisation mass spectrometry (ESMS). The reactivity of 1 towards neutral ligands such as phosphines and pyridines as well as basic metal complexes such as pyridine-thiolate compounds of Au(I), Hg(II) and Pt(II) in solution was also investigated. The results showed that the chloride trans to the Pd-C bond is susceptible to ligand replacement. A number of entry metalloligands was examined in an attempt to establish a route to cyclometallated aggregates and clusters.
Persistent Identifierhttp://hdl.handle.net/10722/219570
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorNeo, Kian Eang-
dc.contributor.authorNeo, Yew Chin-
dc.contributor.authorChien, Sheau Wei-
dc.contributor.authorTan, Geok Kheng-
dc.contributor.authorWilkins, Alistair L.-
dc.contributor.authorHenderson, William-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:25Z-
dc.date.available2015-09-23T02:57:25Z-
dc.date.issued2004-
dc.identifier.citationDalton Transactions, 2004, n. 15, p. 2281-2287-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219570-
dc.description.abstractThe cyclometallated Pd compound PdCl[PPh 2CH 2CH 2CHCH 2CH 2PPh 2] 1, obtained from PdCl 2Ph 2P(CH 2) 5PPh 2) in refluxing DMF (N,N-dimethylformamide), was characterized by NMR and X-ray single-crystal diffraction analysis. The cyclometallation of MCl 2(Ph 2P(CH 2) 5PPh 2) (M = Pd, Pt) to give 1 and its Pt(II) analogue was probed using electrospray ionisation mass spectrometry (ESMS). The reactivity of 1 towards neutral ligands such as phosphines and pyridines as well as basic metal complexes such as pyridine-thiolate compounds of Au(I), Hg(II) and Pt(II) in solution was also investigated. The results showed that the chloride trans to the Pd-C bond is susceptible to ligand replacement. A number of entry metalloligands was examined in an attempt to establish a route to cyclometallated aggregates and clusters.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titlePdCl[PPh 2CH 2CH 2CHCH 2CH 2PPh 2] as a precursor to homo-and hetero-metallic species directed by ESMS (electrospray ionisation mass spectrometry)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-4344646327-
dc.identifier.issue15-
dc.identifier.spage2281-
dc.identifier.epage2287-

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