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Article: Pd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions

TitlePd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions
Authors
Issue Date2008
Citation
Dalton Transactions, 2008, n. 5, p. 699-706 How to Cite?
AbstractNovel Pd(ii) mixed N,S-heterocyclic carbene (NSHC)-phosphine complexes of the general formula [PdBr2(NSHC)(PR3)] were obtained from bridge cleavage of dinuclear NSHC complexes of type [PdBr2(NSHC)] 2 [NSHC = 3-benzylbenzothiazolin-2-ylidene and 3- propylbenzothiazolin-2-ylidene] with triphenylphosphine, tricyclohexylphosphine and 2-diphenylphosphanyl-pyridine. All complexes have been fully characterized by 1H and 13C NMR spectroscopy, ESI mass spectrometry and elemental analysis. The X-ray crystal structures of complexes 3-8 are reported. The complexes exhibit moderate to good catalytic activity in the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides. © The Royal Society of Chemistry 2008.
Persistent Identifierhttp://hdl.handle.net/10722/219562
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorYen, Swee Kuan-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHuynh, Han Vinh-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:24Z-
dc.date.available2015-09-23T02:57:24Z-
dc.date.issued2008-
dc.identifier.citationDalton Transactions, 2008, n. 5, p. 699-706-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219562-
dc.description.abstractNovel Pd(ii) mixed N,S-heterocyclic carbene (NSHC)-phosphine complexes of the general formula [PdBr2(NSHC)(PR3)] were obtained from bridge cleavage of dinuclear NSHC complexes of type [PdBr2(NSHC)] 2 [NSHC = 3-benzylbenzothiazolin-2-ylidene and 3- propylbenzothiazolin-2-ylidene] with triphenylphosphine, tricyclohexylphosphine and 2-diphenylphosphanyl-pyridine. All complexes have been fully characterized by 1H and 13C NMR spectroscopy, ESI mass spectrometry and elemental analysis. The X-ray crystal structures of complexes 3-8 are reported. The complexes exhibit moderate to good catalytic activity in the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides. © The Royal Society of Chemistry 2008.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titlePd(II) complexes with mixed benzothiazolin-2-ylidene and phosphine ligands and their catalytic activities toward C-C coupling reactions-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b713152f-
dc.identifier.scopuseid_2-s2.0-38549124976-
dc.identifier.issue5-
dc.identifier.spage699-
dc.identifier.epage706-
dc.identifier.eissn1477-9234-

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