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Article: Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations

TitleSubstituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations
Authors
Issue Date1987
Citation
Journal of Organometallic Chemistry, 1987, v. 331, n. 1, p. 23-28 How to Cite?
AbstractThe ability of trimethylamine N-oxide as a chemical initiator for facile oxidative decarbonylation in metal carbonyls is manifested by the isolation of M(CO)3(η2-bipy)(η1-dppm) (where M Cr, Mo, W; bipy = 2,2′-bipyridyl; dppm = bis(diphenylphosphino)-methane). The synthetic strategy and spectral (IR and 1H and 31P NMR) characterisations are presented and discussed. Syntheses of the well-known M(CO)4(η2-bipy) have also been modified to give high yields at ambient temperature. © 1987.
Persistent Identifierhttp://hdl.handle.net/10722/219497
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorChee, Sheh Mai-
dc.date.accessioned2015-09-23T02:57:14Z-
dc.date.available2015-09-23T02:57:14Z-
dc.date.issued1987-
dc.identifier.citationJournal of Organometallic Chemistry, 1987, v. 331, n. 1, p. 23-28-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219497-
dc.description.abstractThe ability of trimethylamine N-oxide as a chemical initiator for facile oxidative decarbonylation in metal carbonyls is manifested by the isolation of M(CO)3(η2-bipy)(η1-dppm) (where M Cr, Mo, W; bipy = 2,2′-bipyridyl; dppm = bis(diphenylphosphino)-methane). The synthetic strategy and spectral (IR and 1H and 31P NMR) characterisations are presented and discussed. Syntheses of the well-known M(CO)4(η2-bipy) have also been modified to give high yields at ambient temperature. © 1987.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.titleSubstituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0022-328X(00)98910-1-
dc.identifier.scopuseid_2-s2.0-2742566561-
dc.identifier.volume331-
dc.identifier.issue1-
dc.identifier.spage23-
dc.identifier.epage28-

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