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Article: Interpolymetallic Assembly of d8-d10 Sulfide Aggregates from [Pt2(PPh3)4(μ-S) 2] and Group 12 Metals

TitleInterpolymetallic Assembly of d8-d10 Sulfide Aggregates from [Pt2(PPh3)4(μ-S) 2] and Group 12 Metals
Authors
Issue Date2003
Citation
Inorganic Chemistry, 2003, v. 42, n. 25, p. 8481-8488 How to Cite?
AbstractA series of heterometallic Pt-M (M = Zn and Cd) sulfide aggregates with growing nuclearities {Pt2M}, {Pt4M}, and {Pt 4M2}, viz., [ZnPt2Cl2(PPh 3)4(μ3-S)2] (2), [CdPt 2Cl2(PPh3)4(μ3-S) 2] (3), [Pt2(PPh3)4(μ 3-S)2]2[ZnSO4]2 (4), [Pt2(PPh3)4 (μ3-S) 2]2[CdSO4]2·H2O (5), [CdPt4(PPh3)8(μ3-S) 4][ClO4]2 (7), and [ZnPt4(PPh 3)8(μ3-S)4][ClO4] 2 (8), have been prepared from Pt2(PPh3) 4(μ-S)2 (1) with appropriate zinc and cadmium substrates. The structures have been determined by single-crystal X-ray diffraction. The supporting anions play an active role in the structural assembly process. An unexpected disintegration complex [P t2(S 2CH2)Cl(PPh3)4][PF6] (6) has also been isolated and characterized by single-crystal X-ray diffraction. The mechanism of the formation of 6 is proposed.
Persistent Identifierhttp://hdl.handle.net/10722/219474
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873

 

DC FieldValueLanguage
dc.contributor.authorLi, Zhaohui-
dc.contributor.authorZheng, Weiming-
dc.contributor.authorLiu, Huang-
dc.contributor.authorMok, K. F.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:11Z-
dc.date.available2015-09-23T02:57:11Z-
dc.date.issued2003-
dc.identifier.citationInorganic Chemistry, 2003, v. 42, n. 25, p. 8481-8488-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/219474-
dc.description.abstractA series of heterometallic Pt-M (M = Zn and Cd) sulfide aggregates with growing nuclearities {Pt2M}, {Pt4M}, and {Pt 4M2}, viz., [ZnPt2Cl2(PPh 3)4(μ3-S)2] (2), [CdPt 2Cl2(PPh3)4(μ3-S) 2] (3), [Pt2(PPh3)4(μ 3-S)2]2[ZnSO4]2 (4), [Pt2(PPh3)4 (μ3-S) 2]2[CdSO4]2·H2O (5), [CdPt4(PPh3)8(μ3-S) 4][ClO4]2 (7), and [ZnPt4(PPh 3)8(μ3-S)4][ClO4] 2 (8), have been prepared from Pt2(PPh3) 4(μ-S)2 (1) with appropriate zinc and cadmium substrates. The structures have been determined by single-crystal X-ray diffraction. The supporting anions play an active role in the structural assembly process. An unexpected disintegration complex [P t2(S 2CH2)Cl(PPh3)4][PF6] (6) has also been isolated and characterized by single-crystal X-ray diffraction. The mechanism of the formation of 6 is proposed.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleInterpolymetallic Assembly of d8-d10 Sulfide Aggregates from [Pt2(PPh3)4(μ-S) 2] and Group 12 Metals-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic034884+-
dc.identifier.scopuseid_2-s2.0-0344737651-
dc.identifier.volume42-
dc.identifier.issue25-
dc.identifier.spage8481-
dc.identifier.epage8488-

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