File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au)

TitleSynthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au)
Authors
Issue Date2002
Citation
Inorganic Chemistry, 2002, v. 41, n. 25, p. 6838-6845 How to Cite?
AbstractNovel electroactive multimetallic compounds based on the {Pt2(μ2-S)2M} core, viz. [Pt2(PPh3)4 (μ3-S)2HgFc]PF6 (1) [Fc = (η5-C5H4)Fe(η5- C5H5)] and [Pt2(PPh3)4 (μ3-S)2Hg2Fc′] (PF6)2 (2) [Fc′ = Fe(η5-C5H4)2], have been synthesized under the guide of electrospray mass spectrometry. The electrochemistry of these ferrocene funtionalized compounds together with the reported [Pt2(PPh3)4 (μ3-S)2HgPPh3] (PF6)2 (3), [Pt2(PPh3)4(μ2-S) (μ3-S)HgPh]PF6 (4), and [Pt2(PPh3)4-(μ2-S) (μ3-S)AuPPh3]PF6 (5) have been investigated using cyclic voltammetry and DFT calculations. These results point to a prominent ligand-based oxidation.
Persistent Identifierhttp://hdl.handle.net/10722/219461
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873

 

DC FieldValueLanguage
dc.contributor.authorXu, Xingling-
dc.contributor.authorAudi Fong, S. W.-
dc.contributor.authorLi, Zhaohui-
dc.contributor.authorLoh, Zhi Heng-
dc.contributor.authorZhao, Feng-
dc.contributor.authorVittal, Jagadese J.-
dc.contributor.authorHenderson, William-
dc.contributor.authorKhoo, Soo Beng-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:08Z-
dc.date.available2015-09-23T02:57:08Z-
dc.date.issued2002-
dc.identifier.citationInorganic Chemistry, 2002, v. 41, n. 25, p. 6838-6845-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/219461-
dc.description.abstractNovel electroactive multimetallic compounds based on the {Pt2(μ2-S)2M} core, viz. [Pt2(PPh3)4 (μ3-S)2HgFc]PF6 (1) [Fc = (η5-C5H4)Fe(η5- C5H5)] and [Pt2(PPh3)4 (μ3-S)2Hg2Fc′] (PF6)2 (2) [Fc′ = Fe(η5-C5H4)2], have been synthesized under the guide of electrospray mass spectrometry. The electrochemistry of these ferrocene funtionalized compounds together with the reported [Pt2(PPh3)4 (μ3-S)2HgPPh3] (PF6)2 (3), [Pt2(PPh3)4(μ2-S) (μ3-S)HgPh]PF6 (4), and [Pt2(PPh3)4-(μ2-S) (μ3-S)AuPPh3]PF6 (5) have been investigated using cyclic voltammetry and DFT calculations. These results point to a prominent ligand-based oxidation.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleSynthetic, structural, electrochemical, and theoretical studies of heterometallic aggregates with a [Pt2(μ-S)2M] core (M = Hg, Au)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic011181o-
dc.identifier.pmid12470082-
dc.identifier.scopuseid_2-s2.0-0037121895-
dc.identifier.volume41-
dc.identifier.issue25-
dc.identifier.spage6838-
dc.identifier.epage6845-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats