File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Amine-oxide-mediated reactions of Re2(CO)10 with phenol and aliphatic alcohols: The formation of Re3(CO)14(μ-H) and a hydroxo-methoxo trirhenium aggregate [Me3NH]+[Re3(CO)9(μ-OH)2(μ-OMe)(μ3-OMe)]-

TitleAmine-oxide-mediated reactions of Re2(CO)10 with phenol and aliphatic alcohols: The formation of Re3(CO)14(μ-H) and a hydroxo-methoxo trirhenium aggregate [Me3NH]+[Re3(CO)9(μ-OH)2(μ-OMe)(μ3-OMe)]-
Authors
KeywordsProtolysis
Carbonyl-hydroxo-alkoxo-complex
Decarbonylation
Dirhenium decacarbonyl
Hydride
Trimethylamine N-oxide
Issue Date1997
Citation
Journal of Organometallic Chemistry, 1997, v. 543, n. 1-2, p. 179-188 How to Cite?
AbstractOxidative decarbonylation of Re2(CO)10 by Me3NO in a mixture of THF and phenol resulted in Re3(CO)14(μ-H), 1, and [Me3NH]+[Re2(CO)6(μ-OPh)3]-, 2, in 30 and 17% yields respectively. In the analogous reaction in THF-MeOH mixture, a trinuclear complex, [Me3NH]+[Re3(CO)9(μ-OH)2(μ-OMe)(μ3-OMe)]-, 3, was isolated instead. The structure of 3 was determined by single-crystal X-ray diffraction analysis: orthorhombic, space group Ama2, a = 14.022(2), b = 18.003(5), c = 9.601(2) Å, final R = 0.031 for 958 reflections. The anion contains a Re3 triangle edge-bridged by one methoxy and two hydroxy ligands and capped by a methoxy group. No formal Re-Re bond (Re ⋯ Re 3.423 and 3.439 Å) is envisaged. Possible mechanisms for the formation of 1, 2 and 3 are proposed. © 1997 Elsevier Science S.A.
Persistent Identifierhttp://hdl.handle.net/10722/219429
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorJiang, Chenghua-
dc.contributor.authorWen, Yuh Sheng-
dc.contributor.authorLiu, Ling Kang-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorYan, Yaw Kai-
dc.date.accessioned2015-09-23T02:57:03Z-
dc.date.available2015-09-23T02:57:03Z-
dc.date.issued1997-
dc.identifier.citationJournal of Organometallic Chemistry, 1997, v. 543, n. 1-2, p. 179-188-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219429-
dc.description.abstractOxidative decarbonylation of Re2(CO)10 by Me3NO in a mixture of THF and phenol resulted in Re3(CO)14(μ-H), 1, and [Me3NH]+[Re2(CO)6(μ-OPh)3]-, 2, in 30 and 17% yields respectively. In the analogous reaction in THF-MeOH mixture, a trinuclear complex, [Me3NH]+[Re3(CO)9(μ-OH)2(μ-OMe)(μ3-OMe)]-, 3, was isolated instead. The structure of 3 was determined by single-crystal X-ray diffraction analysis: orthorhombic, space group Ama2, a = 14.022(2), b = 18.003(5), c = 9.601(2) Å, final R = 0.031 for 958 reflections. The anion contains a Re3 triangle edge-bridged by one methoxy and two hydroxy ligands and capped by a methoxy group. No formal Re-Re bond (Re ⋯ Re 3.423 and 3.439 Å) is envisaged. Possible mechanisms for the formation of 1, 2 and 3 are proposed. © 1997 Elsevier Science S.A.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectProtolysis-
dc.subjectCarbonyl-hydroxo-alkoxo-complex-
dc.subjectDecarbonylation-
dc.subjectDirhenium decacarbonyl-
dc.subjectHydride-
dc.subjectTrimethylamine N-oxide-
dc.titleAmine-oxide-mediated reactions of Re2(CO)10 with phenol and aliphatic alcohols: The formation of Re3(CO)14(μ-H) and a hydroxo-methoxo trirhenium aggregate [Me3NH]+[Re3(CO)9(μ-OH)2(μ-OMe)(μ3-OMe)]--
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0031591862-
dc.identifier.volume543-
dc.identifier.issue1-2-
dc.identifier.spage179-
dc.identifier.epage188-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats