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Article: High-performance liquid chromatography of Group 6 dimetal decacarbonyl complexes singly-bridged by diphosphine ligands

TitleHigh-performance liquid chromatography of Group 6 dimetal decacarbonyl complexes singly-bridged by diphosphine ligands
Authors
Issue Date1994
Citation
Journal of Liquid Chromatography, 1994, v. 17, n. 17, p. 3671-3680 How to Cite?
AbstractThe normal-phase high-performance liquid chromatography of a series of Group 6 dimetal decacarbonyl complexes, of the form (OC)5M(P(CH2)(n)P)M(CO)5, where M = Cr, Mo and W, and P(CH2)(n)P = diphenylphosphinyl bridge with n = 2-6, is reported. Chromatography was carried out on a stainless steel column packed with silica to which polar amino-cyano groups have been bonded; hexane-chloroform was used as mobile phase. The retention behaviour of these homometallic complexes is discussed. | The normal-phase high-performance liquid chromatography of a series of Group 6 dimetal decacarbonyl complexes, of the form (OC)5M(P(CH2)nP)M(CO)5, where M = Cr, Mo and W, and P(CH2)nP = diphenylphosphinyl bridge with n = 2-6, is reported. Chromatography was carried out on a stainless steel column packed with silica to which polar amino-cyano groups have been bonded; hexane-chloroform was used as mobile phase. The retention behaviour of these homometallic complexes is discussed.
Persistent Identifierhttp://hdl.handle.net/10722/219415
ISSN

 

DC FieldValueLanguage
dc.contributor.authorTan, K. C.-
dc.contributor.authorHor, T. S A-
dc.contributor.authorLee, H. K.-
dc.date.accessioned2015-09-23T02:57:00Z-
dc.date.available2015-09-23T02:57:00Z-
dc.date.issued1994-
dc.identifier.citationJournal of Liquid Chromatography, 1994, v. 17, n. 17, p. 3671-3680-
dc.identifier.issn0148-3919-
dc.identifier.urihttp://hdl.handle.net/10722/219415-
dc.description.abstractThe normal-phase high-performance liquid chromatography of a series of Group 6 dimetal decacarbonyl complexes, of the form (OC)5M(P(CH2)(n)P)M(CO)5, where M = Cr, Mo and W, and P(CH2)(n)P = diphenylphosphinyl bridge with n = 2-6, is reported. Chromatography was carried out on a stainless steel column packed with silica to which polar amino-cyano groups have been bonded; hexane-chloroform was used as mobile phase. The retention behaviour of these homometallic complexes is discussed. | The normal-phase high-performance liquid chromatography of a series of Group 6 dimetal decacarbonyl complexes, of the form (OC)5M(P(CH2)nP)M(CO)5, where M = Cr, Mo and W, and P(CH2)nP = diphenylphosphinyl bridge with n = 2-6, is reported. Chromatography was carried out on a stainless steel column packed with silica to which polar amino-cyano groups have been bonded; hexane-chloroform was used as mobile phase. The retention behaviour of these homometallic complexes is discussed.-
dc.languageeng-
dc.relation.ispartofJournal of Liquid Chromatography-
dc.titleHigh-performance liquid chromatography of Group 6 dimetal decacarbonyl complexes singly-bridged by diphosphine ligands-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0028518661-
dc.identifier.volume17-
dc.identifier.issue17-
dc.identifier.spage3671-
dc.identifier.epage3680-

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