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Article: Entrapping of organic wastes by coordination clathrates

TitleEntrapping of organic wastes by coordination clathrates
Authors
Issue Date1991
Citation
Environmental Monitoring and Assessment, 1991, v. 19, n. 1-3, p. 145-150 How to Cite?
AbstractThe feasibility of the Hofmann clathrates Ni(CN)2(NH3)·G(G=guest molecule) and the octahedral Werner-type complexes Ni(X)2(L)4 (X=NCS, NCO, CH3CO2, C6H5CO2; L=Py, 4-Mepy) as a scavenger for organic substrates in a polluted aqueous or organic medium is dependent on the complex lability, thermal stability and reversibility in solvent trapping which can be conveniently studied by thermogravimetric means. Besides the parent monomeric octahedral complexes, all the thermal decompositional intermediates, namely, monomeric tetrahedral, dimeric octahedral and polymeric octahedral, are also potential scavengers for selected organic substances though they operate via a cycle of bond-making and bond-breaking processes. © 1991 Kluwer Academic Publishers.
Persistent Identifierhttp://hdl.handle.net/10722/219401
ISSN
2015 Impact Factor: 1.633
2015 SCImago Journal Rankings: 0.634

 

DC FieldValueLanguage
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorLeong, Ying Phooi-
dc.contributor.authorPhang, Lai Tee-
dc.date.accessioned2015-09-23T02:56:58Z-
dc.date.available2015-09-23T02:56:58Z-
dc.date.issued1991-
dc.identifier.citationEnvironmental Monitoring and Assessment, 1991, v. 19, n. 1-3, p. 145-150-
dc.identifier.issn0167-6369-
dc.identifier.urihttp://hdl.handle.net/10722/219401-
dc.description.abstractThe feasibility of the Hofmann clathrates Ni(CN)2(NH3)·G(G=guest molecule) and the octahedral Werner-type complexes Ni(X)2(L)4 (X=NCS, NCO, CH3CO2, C6H5CO2; L=Py, 4-Mepy) as a scavenger for organic substrates in a polluted aqueous or organic medium is dependent on the complex lability, thermal stability and reversibility in solvent trapping which can be conveniently studied by thermogravimetric means. Besides the parent monomeric octahedral complexes, all the thermal decompositional intermediates, namely, monomeric tetrahedral, dimeric octahedral and polymeric octahedral, are also potential scavengers for selected organic substances though they operate via a cycle of bond-making and bond-breaking processes. © 1991 Kluwer Academic Publishers.-
dc.languageeng-
dc.relation.ispartofEnvironmental Monitoring and Assessment-
dc.titleEntrapping of organic wastes by coordination clathrates-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1007/BF00401306-
dc.identifier.scopuseid_2-s2.0-0025840465-
dc.identifier.volume19-
dc.identifier.issue1-3-
dc.identifier.spage145-
dc.identifier.epage150-
dc.identifier.eissn1573-2959-

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