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Conference Paper: Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings

TitleFerrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings
Authors
KeywordsFerrocenyl
Suzuki cross-coupling
Phosphine
Palladium
Issue Date2011
Citation
Journal of Organometallic Chemistry, 2011, v. 696, n. 17, p. 2928-2934 How to Cite?
AbstractA mixture of Pd2(dba)3/{η-C5H 4CHN[CH(CH3)(Nap)]}Fe[η-C5H 4P(tBu)2] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 × 10-6-1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd 2(dba)3, the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. © 2011 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219378
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorTeo, Shihui-
dc.contributor.authorWeng, Zhiqiang-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:55Z-
dc.date.available2015-09-23T02:56:55Z-
dc.date.issued2011-
dc.identifier.citationJournal of Organometallic Chemistry, 2011, v. 696, n. 17, p. 2928-2934-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219378-
dc.description.abstractA mixture of Pd2(dba)3/{η-C5H 4CHN[CH(CH3)(Nap)]}Fe[η-C5H 4P(tBu)2] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 × 10-6-1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd 2(dba)3, the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. © 2011 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectFerrocenyl-
dc.subjectSuzuki cross-coupling-
dc.subjectPhosphine-
dc.subjectPalladium-
dc.titleFerrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings-
dc.typeConference_Paper-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2011.04.031-
dc.identifier.scopuseid_2-s2.0-79960106122-
dc.identifier.volume696-
dc.identifier.issue17-
dc.identifier.spage2928-
dc.identifier.epage2934-

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