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Article: Self-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine)

TitleSelf-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine)
Authors
Issue Date2008
Citation
Dalton Transactions, 2008, n. 46, p. 6619-6623 How to Cite?
AbstractThe high reactivity of Group 10 metal-metal bonded complexes towards platinum chalcogenide compounds have been demonstrated through the successful isolation of a number of novel homo- and hetero-polynuclear complexes. A d 8-d9 pentanuclear sulfide cluster with a Pd3 triangle sandwiched by two Pt2 sheaths with peripheral protection from coordinated and pendant pyridyls has been isolated and characterized. Other related aggregates with the {Pt2M2X2} (X = S, Se) core have also been obtained from the addition of the [Pt2S 2] metalloligand to dinuclear Pd(I). © 2008 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219370
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorLi, Jingqiu-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:56:54Z-
dc.date.available2015-09-23T02:56:54Z-
dc.date.issued2008-
dc.identifier.citationDalton Transactions, 2008, n. 46, p. 6619-6623-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219370-
dc.description.abstractThe high reactivity of Group 10 metal-metal bonded complexes towards platinum chalcogenide compounds have been demonstrated through the successful isolation of a number of novel homo- and hetero-polynuclear complexes. A d 8-d9 pentanuclear sulfide cluster with a Pd3 triangle sandwiched by two Pt2 sheaths with peripheral protection from coordinated and pendant pyridyls has been isolated and characterized. Other related aggregates with the {Pt2M2X2} (X = S, Se) core have also been obtained from the addition of the [Pt2S 2] metalloligand to dinuclear Pd(I). © 2008 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleSelf-selected formation of a heteropolymetallic sandwich [Pd 3Pt4(μ3-S)4(μ-dppy) 4(dppy)4][PF6]3 from dinuclear addition across the [Pt2] and [Pd2] cores (dppy = 2-(diphenylphosphino)pyridine)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b812644e-
dc.identifier.scopuseid_2-s2.0-56849099606-
dc.identifier.issue46-
dc.identifier.spage6619-
dc.identifier.epage6623-
dc.identifier.eissn1477-9234-

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