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Article: Synthesis of cyclogentiotriose by macrocyclization via a ring-closing glycosylation

TitleSynthesis of cyclogentiotriose by macrocyclization via a ring-closing glycosylation
Authors
Liu, HLi, X
KeywordsRing-closing glycosylation
β-Selectivity
Macrocyclization
Cyclogentiotriose
Issue Date2014
PublisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet
Citation
Tetrahedron Letters, 2014, v. 55 n. 40, p. 5525-5528 How to Cite?
DOI: http://dx.doi.org/10.1016/j.tetlet.2014.08.063
AbstractThe synthesis of a benzylated cyclogentiotriose was achieved through the ring-closing glycosylation, which was developed by us recently. Moderate β-selectivity (3.3:1) was obtained in the 1,6 glycosidic linkage formation step. The α-acetoxy ether precursor was generated through the Rychnovsky reductive acetylation of a linear trisaccharide derived macrolactone.
Persistent Identifierhttp://hdl.handle.net/10722/210690
ISSN
0040-4039
2021 Impact Factor: 2.032
2020 SCImago Journal Rankings: 0.541
ISI Accession Number ID
WOS:000342871800028

 

DC FieldValueLanguage
dc.contributor.authorLiu, H-
dc.contributor.authorLi, X-
dc.date.accessioned2015-06-23T05:47:15Z-
dc.date.available2015-06-23T05:47:15Z-
dc.date.issued2014-
dc.identifier.citationTetrahedron Letters, 2014, v. 55 n. 40, p. 5525-5528-
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10722/210690-
dc.description.abstractThe synthesis of a benzylated cyclogentiotriose was achieved through the ring-closing glycosylation, which was developed by us recently. Moderate β-selectivity (3.3:1) was obtained in the 1,6 glycosidic linkage formation step. The α-acetoxy ether precursor was generated through the Rychnovsky reductive acetylation of a linear trisaccharide derived macrolactone.-
dc.languageeng-
dc.publisherPergamon. The Journal's web site is located at http://www.elsevier.com/locate/tetlet-
dc.relation.ispartofTetrahedron Letters-
dc.subjectRing-closing glycosylation-
dc.subjectβ-Selectivity-
dc.subjectMacrocyclization-
dc.subjectCyclogentiotriose-
dc.titleSynthesis of cyclogentiotriose by macrocyclization via a ring-closing glycosylation-
dc.typeArticle-
dc.identifier.emailLiu, H: liuhan@hku.hk-
dc.identifier.emailLi, X: xuechenl@hku.hk-
dc.identifier.authorityLiu, H=rp02748-
dc.identifier.authorityLi, X=rp00742-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.tetlet.2014.08.063-
dc.identifier.scopuseid_2-s2.0-84908662341-
dc.identifier.hkuros243696-
dc.identifier.volume55-
dc.identifier.issue40-
dc.identifier.spage5525-
dc.identifier.epage5528-
dc.identifier.isiWOS:000342871800028-
dc.publisher.placeUnited Kingdom-
dc.identifier.issnl0040-4039-

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