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Conference Paper: Oxidation of hydrocarbons by ruthenium-oxo complexes

TitleOxidation of hydrocarbons by ruthenium-oxo complexes
Authors
Issue Date1990
Citation
American Chemical Society, Division Of Petroleum Chemistry, Preprints Symposia, 1990, v. 35 n. 2, p. 179-186 How to Cite?
AbstractSelective oxidation of saturated hydrocarbons to the corresponding alcohols/ketones under mild conditions still remains one of the most important challenges in homogeneous catalysis. Among the transition metal complexes investigated, those oxo complexes of ruthenium and manganese are found to be very reactive, capable of oxidizing saturated alkanes under suitable choice of reaction conditions. However, there is still a lack of understanding of the factors governing the rate of alkane oxidation because the reactive manganese and ruthenium-oxo species are very difficult to be generated and characterized. In this paper, an overall picture of the reactivities of ruthenium-oxo complexes with π-aromatic diimines, macrocyclic tertiary amines, and porphyrins as ligands is discussed.
Persistent Identifierhttp://hdl.handle.net/10722/168793
ISSN
2008 SCImago Journal Rankings: 0.145

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorHo, Cen_US
dc.contributor.authorLee, WOen_US
dc.contributor.authorLau, TCen_US
dc.date.accessioned2012-10-08T03:34:17Z-
dc.date.available2012-10-08T03:34:17Z-
dc.date.issued1990en_US
dc.identifier.citationAmerican Chemical Society, Division Of Petroleum Chemistry, Preprints Symposia, 1990, v. 35 n. 2, p. 179-186en_US
dc.identifier.issn0569-3799en_US
dc.identifier.urihttp://hdl.handle.net/10722/168793-
dc.description.abstractSelective oxidation of saturated hydrocarbons to the corresponding alcohols/ketones under mild conditions still remains one of the most important challenges in homogeneous catalysis. Among the transition metal complexes investigated, those oxo complexes of ruthenium and manganese are found to be very reactive, capable of oxidizing saturated alkanes under suitable choice of reaction conditions. However, there is still a lack of understanding of the factors governing the rate of alkane oxidation because the reactive manganese and ruthenium-oxo species are very difficult to be generated and characterized. In this paper, an overall picture of the reactivities of ruthenium-oxo complexes with π-aromatic diimines, macrocyclic tertiary amines, and porphyrins as ligands is discussed.en_US
dc.languageengen_US
dc.relation.ispartofAmerican Chemical Society, Division of Petroleum Chemistry, Preprints Symposiaen_US
dc.titleOxidation of hydrocarbons by ruthenium-oxo complexesen_US
dc.typeConference_Paperen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-0025412308en_US
dc.identifier.volume35en_US
dc.identifier.issue2en_US
dc.identifier.spage179en_US
dc.identifier.epage186en_US
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridHo, C=7404652540en_US
dc.identifier.scopusauthoridLee, WO=7407087172en_US
dc.identifier.scopusauthoridLau, TC=7102222310en_US

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