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Article: Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand
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TitleHighly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand
 
AuthorsWang, JC2
Xu, ZJ2
Guo, Z1
Deng, QH2
Zhou, CY1
Wan, XL2
Che, CM2 1
 
Issue Date2012
 
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
 
CitationChemical Communications, 2012, v. 48 n. 36, p. 4299-4301 [How to Cite?]
DOI: http://dx.doi.org/10.1039/c2cc30441d
 
AbstractThe chiral iridium porphyrin [Ir((-)-D 4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee). © The Royal Society of Chemistry 2012.
 
ISSN1359-7345
2013 Impact Factor: 6.718
2013 SCImago Journal Rankings: 2.918
 
DOIhttp://dx.doi.org/10.1039/c2cc30441d
 
ReferencesReferences in Scopus
 
DC FieldValue
dc.contributor.authorWang, JC
 
dc.contributor.authorXu, ZJ
 
dc.contributor.authorGuo, Z
 
dc.contributor.authorDeng, QH
 
dc.contributor.authorZhou, CY
 
dc.contributor.authorWan, XL
 
dc.contributor.authorChe, CM
 
dc.date.accessioned2012-10-08T03:21:41Z
 
dc.date.available2012-10-08T03:21:41Z
 
dc.date.issued2012
 
dc.description.abstractThe chiral iridium porphyrin [Ir((-)-D 4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee). © The Royal Society of Chemistry 2012.
 
dc.description.natureLink_to_subscribed_fulltext
 
dc.identifier.citationChemical Communications, 2012, v. 48 n. 36, p. 4299-4301 [How to Cite?]
DOI: http://dx.doi.org/10.1039/c2cc30441d
 
dc.identifier.doihttp://dx.doi.org/10.1039/c2cc30441d
 
dc.identifier.epage4301
 
dc.identifier.hkuros204518
 
dc.identifier.issn1359-7345
2013 Impact Factor: 6.718
2013 SCImago Journal Rankings: 2.918
 
dc.identifier.issue36
 
dc.identifier.pmid22447038
 
dc.identifier.scopuseid_2-s2.0-84859587639
 
dc.identifier.spage4299
 
dc.identifier.urihttp://hdl.handle.net/10722/168620
 
dc.identifier.volume48
 
dc.languageeng
 
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
 
dc.publisher.placeUnited Kingdom
 
dc.relation.ispartofChemical Communications
 
dc.relation.referencesReferences in Scopus
 
dc.subject.meshCarbon - chemistry
 
dc.subject.meshHydrogen - chemistry
 
dc.subject.meshIridium - chemistry
 
dc.subject.meshMetalloporphyrins - chemistry
 
dc.subject.meshMethane - analogs and derivatives - chemistry
 
dc.titleHighly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand
 
dc.typeArticle
 
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Author Affiliations
  1. Institute of Molecular Technology for Drug Discovery and Synthesis, Hong Kong
  2. Shanghai Institute of Organic Chemistry Chinese Academy of Sciences