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Article: Highly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand

TitleHighly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin ligand
Authors
Issue Date2012
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2012, v. 48 n. 36, p. 4299-4301 How to Cite?
AbstractThe chiral iridium porphyrin [Ir((-)-D 4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee). © The Royal Society of Chemistry 2012.
Persistent Identifierhttp://hdl.handle.net/10722/168620
ISSN
2014 Impact Factor: 6.834
2014 SCImago Journal Rankings: 2.444
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWang, JCen_US
dc.contributor.authorXu, ZJen_US
dc.contributor.authorGuo, Zen_US
dc.contributor.authorDeng, QHen_US
dc.contributor.authorZhou, CYen_US
dc.contributor.authorWan, XLen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:21:41Z-
dc.date.available2012-10-08T03:21:41Z-
dc.date.issued2012en_US
dc.identifier.citationChemical Communications, 2012, v. 48 n. 36, p. 4299-4301en_US
dc.identifier.issn1359-7345en_US
dc.identifier.urihttp://hdl.handle.net/10722/168620-
dc.description.abstractThe chiral iridium porphyrin [Ir((-)-D 4-Por*)(Me)(EtOH)] displays excellent reactivity and stereoselectivity towards carbene insertion to C-H and Si-H bonds, affording corresponding products in high yields (up to 96%) and high enantioselectivities (up to 98% ee). © The Royal Society of Chemistry 2012.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofChemical Communicationsen_US
dc.subject.meshCarbon - chemistry-
dc.subject.meshHydrogen - chemistry-
dc.subject.meshIridium - chemistry-
dc.subject.meshMetalloporphyrins - chemistry-
dc.subject.meshMethane - analogs and derivatives - chemistry-
dc.titleHighly enantioselective intermolecular carbene insertion to C-H and Si-H bonds catalyzed by a chiral iridium(iii) complex of a D 4-symmetric Halterman porphyrin liganden_US
dc.typeArticleen_US
dc.identifier.emailZhou, CY:cyzhou@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityZhou, CY=rp00843en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/c2cc30441den_US
dc.identifier.pmid22447038-
dc.identifier.scopuseid_2-s2.0-84859587639en_US
dc.identifier.hkuros204518-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-84859587639&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume48en_US
dc.identifier.issue36en_US
dc.identifier.spage4299en_US
dc.identifier.epage4301en_US
dc.identifier.isiWOS:000302363400007-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridWang, JC=52464857400en_US
dc.identifier.scopusauthoridXu, ZJ=8708548900en_US
dc.identifier.scopusauthoridGuo, Z=36554069300en_US
dc.identifier.scopusauthoridDeng, QH=8987982900en_US
dc.identifier.scopusauthoridZhou, CY=35742480200en_US
dc.identifier.scopusauthoridWan, XL=55180731300en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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