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Article: Thermal and photochemical reactions of azidoruthenium(III) complexes of macrocyclic tertiary amines and the structure of the (phosphoraniminato) ruthenium(III) complex trans-[Ru(14-TMC)(N 3)(NPPh 3)] +

TitleThermal and photochemical reactions of azidoruthenium(III) complexes of macrocyclic tertiary amines and the structure of the (phosphoraniminato) ruthenium(III) complex trans-[Ru(14-TMC)(N 3)(NPPh 3)] +
Authors
KeywordsAzides
Macrocyclic ligands
N ligands
Nitrides
Ruthenium
Issue Date2012
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.org
Citation
European Journal Of Inorganic Chemistry, 2012 n. 1, p. 151-159 How to Cite?
AbstractThe bis(azido)ruthenium(III) complexes, trans-[Ru(L)(N 3) 2] + [L = 14-TMC (1) and 16-TMC (4)] have been prepared. These complexes undergo facile thermal or photo-decomposition in RCN (R = Me, Bu, Ph, 4-MePh, 2-MeOPh) solutions to produce the corresponding azidoruthenium(II) complexes trans-[Ru(L)(N 3)(RCN)] + [L = 14-TMC, R = Me (2a), Bu (2b), Ph (2c), 4-MePh (2d), 2-MeOPh (2e); L = 16-TMC, R = Me (5a), = Ph (5b)] and cis-[Ru(Tet-Me 6)(N 3)(MeCN)] + (6). Complex 1 reacted with PPh 3, by a nitrogen atom transfer reaction, to give trans-[Ru(14-TMC)(N 3)(NPPh 3)] + (3) in 80 % yield. The crystal structures of 2e(PF 6), 3(PF 6) and 5b(ClO 4) have been determined by X-ray diffraction analysis. Complex 3 is the first structurally characterized (phosphoraniminato)ruthenium(III) complex with Ru-N distances of 1.991(7)-2.014(6) Å and a nearly linear Ru-N-P moiety [[ang]Ru-N-P = 168.2(5)-171.5(6)°]. Density functional theory (DFT) calculations on 3 and the proposed [Ru V(14-TMC)(N)(N 3)] + intermediate have been performed.
Persistent Identifierhttp://hdl.handle.net/10722/168598
ISSN
2015 Impact Factor: 2.686
2015 SCImago Journal Rankings: 1.018
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorHo, CMen_HK
dc.contributor.authorLeung, HCen_HK
dc.contributor.authorWu, Sen_HK
dc.contributor.authorLow, KHen_HK
dc.contributor.authorLin, Zen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-10-08T03:21:21Z-
dc.date.available2012-10-08T03:21:21Z-
dc.date.issued2012en_HK
dc.identifier.citationEuropean Journal Of Inorganic Chemistry, 2012 n. 1, p. 151-159en_HK
dc.identifier.issn1434-1948en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168598-
dc.description.abstractThe bis(azido)ruthenium(III) complexes, trans-[Ru(L)(N 3) 2] + [L = 14-TMC (1) and 16-TMC (4)] have been prepared. These complexes undergo facile thermal or photo-decomposition in RCN (R = Me, Bu, Ph, 4-MePh, 2-MeOPh) solutions to produce the corresponding azidoruthenium(II) complexes trans-[Ru(L)(N 3)(RCN)] + [L = 14-TMC, R = Me (2a), Bu (2b), Ph (2c), 4-MePh (2d), 2-MeOPh (2e); L = 16-TMC, R = Me (5a), = Ph (5b)] and cis-[Ru(Tet-Me 6)(N 3)(MeCN)] + (6). Complex 1 reacted with PPh 3, by a nitrogen atom transfer reaction, to give trans-[Ru(14-TMC)(N 3)(NPPh 3)] + (3) in 80 % yield. The crystal structures of 2e(PF 6), 3(PF 6) and 5b(ClO 4) have been determined by X-ray diffraction analysis. Complex 3 is the first structurally characterized (phosphoraniminato)ruthenium(III) complex with Ru-N distances of 1.991(7)-2.014(6) Å and a nearly linear Ru-N-P moiety [[ang]Ru-N-P = 168.2(5)-171.5(6)°]. Density functional theory (DFT) calculations on 3 and the proposed [Ru V(14-TMC)(N)(N 3)] + intermediate have been performed.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.eurjic.orgen_HK
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_HK
dc.subjectAzidesen_HK
dc.subjectMacrocyclic ligandsen_HK
dc.subjectN ligandsen_HK
dc.subjectNitridesen_HK
dc.subjectRutheniumen_HK
dc.titleThermal and photochemical reactions of azidoruthenium(III) complexes of macrocyclic tertiary amines and the structure of the (phosphoraniminato) ruthenium(III) complex trans-[Ru(14-TMC)(N 3)(NPPh 3)] +en_HK
dc.typeArticleen_HK
dc.identifier.emailHo, CM: rickyho@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityHo, CM=rp00705en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/ejic.201100771en_HK
dc.identifier.scopuseid_2-s2.0-84555218203en_HK
dc.identifier.hkuros205212-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-84555218203&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.issue1en_HK
dc.identifier.spage151en_HK
dc.identifier.epage159en_HK
dc.identifier.isiWOS:000301488500019-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridHo, CM=12807243800en_HK
dc.identifier.scopusauthoridLeung, HC=36504260400en_HK
dc.identifier.scopusauthoridWu, S=24386017200en_HK
dc.identifier.scopusauthoridLow, KH=7102180516en_HK
dc.identifier.scopusauthoridLin, Z=7404230177en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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