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Article: Trapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO 2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction

TitleTrapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO 2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reaction
Authors
KeywordsCarbenoids
Porphyrinoids
Reactive intermediates
Ruthenium
Structure elucidation
Issue Date2009
PublisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry
Citation
Chemistry - A European Journal, 2009, v. 15 n. 41, p. 10707-10712 How to Cite?
AbstractWhat's in my pockets? By employing Suslick's bis-pocket porphyrin (ttppp), a reactive M=CHCO 2Et complex and a trans-[M(CHR)(CO)] (M = Ru) complex have been structurally characterized by X-ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin-catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/168410
ISSN
2015 Impact Factor: 5.771
2015 SCImago Journal Rankings: 2.323
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorDeng, QHen_HK
dc.contributor.authorChen, Jen_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorLi, GYen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-10-08T03:18:36Z-
dc.date.available2012-10-08T03:18:36Z-
dc.date.issued2009en_HK
dc.identifier.citationChemistry - A European Journal, 2009, v. 15 n. 41, p. 10707-10712en_HK
dc.identifier.issn0947-6539en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168410-
dc.description.abstractWhat's in my pockets? By employing Suslick's bis-pocket porphyrin (ttppp), a reactive M=CHCO 2Et complex and a trans-[M(CHR)(CO)] (M = Ru) complex have been structurally characterized by X-ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin-catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistryen_HK
dc.relation.ispartofChemistry - A European Journalen_HK
dc.subjectCarbenoidsen_HK
dc.subjectPorphyrinoidsen_HK
dc.subjectReactive intermediatesen_HK
dc.subjectRutheniumen_HK
dc.subjectStructure elucidationen_HK
dc.subject.meshCrystallography, X-Rayen_US
dc.subject.meshMethane - Analogs & Derivatives - Chemistryen_US
dc.subject.meshMolecular Conformationen_US
dc.subject.meshMolecular Structureen_US
dc.subject.meshPorphyrins - Chemical Synthesis - Chemistryen_US
dc.subject.meshRuthenium - Chemistryen_US
dc.subject.meshStereoisomerismen_US
dc.titleTrapping reactive metal-carbene complexes by a bis-pocket porphyrin: X-ray crystal structures of Ru=CHCO 2et and trans-[Ru(CHR)(CO)] species and highly selective carbenoid transfer reactionen_HK
dc.typeArticleen_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/chem.200901895en_HK
dc.identifier.pmid19760736-
dc.identifier.scopuseid_2-s2.0-70350233362en_HK
dc.identifier.hkuros159123-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-70350233362&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume15en_HK
dc.identifier.issue41en_HK
dc.identifier.spage10707en_HK
dc.identifier.epage10712en_HK
dc.identifier.eissn1521-3765-
dc.identifier.isiWOS:000271605900003-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridDeng, QH=8987982900en_HK
dc.identifier.scopusauthoridChen, J=36047378100en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridLi, GY=40261792700en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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