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Article: Synthesis and characterization of bis(amine) Iron (II) porphyrins
Title | Synthesis and characterization of bis(amine) Iron (II) porphyrins 鐵(Ⅱ)卟啉二胺配合物的合成和表征 |
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Authors | |
Keywords | Amine (胺) Bis(Amine)Iron(II) Porphyrin (鐵(Ⅱ)卟啉二胺) Synthesis (合成) |
Issue Date | 1997 |
Publisher | Editorial office of Chemical Journal of Chinese Universities(高等學校化學學報編輯部). The Journal's web site is located at http://www.cjcu.jlu.edu.cn/ |
Citation | Chemical Journal Of Chinese Universities, 1997, v. 18 n. 3, p. 357-359 How to Cite? 高等學校化學學报, 1997, v. 18 n. 3, p. 357-359 How to Cite? |
Abstract | A series of bis(amine) iron( II ) porphyrin Fe( II ) TPP(NH 2R) 2 complexes (NH 2R = PhNH 2, C 6H 11NH 2, n-BuNH 2, PhCH 2NH 2, NHMe 2; TPP = dianion of wwo-tetraphenylporphyrin ) were prepared by the reduction of Fe ( II ) porphyrins with the corresponding amine in an antiformin system in air as well as by the sodium borohydride reduction method, respectively. The complexes were charaterized by UV-Vis, IR and elementary analysis, and some important properties of them were discussed. 已報道合成的二價鐵葉琳配合物主要集中在毗陡、咪唑、NO等配體上.有機胺雖然是配位化學中一類極為經典的配體,但合成金屬葉琳胺類配合物的報道卻為數甚少,據我們所知,僅限於Ru[1]、Rh[3]、Os[3]等配合物.迄今還未見合成鐵(Ⅱ)卟啉胺類的報道.本文通過引入強氧化劑安替福民, 實現了在含水含氧體系中合成2價鐵葉琳胺配合物, 為2價鐵葉琳配合物的合成開闢了一條新的途徑 |
Persistent Identifier | http://hdl.handle.net/10722/168361 |
ISSN | 2021 Impact Factor: 0.786 2020 SCImago Journal Rankings: 0.149 |
References |
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Zhong, XH | en_US |
dc.contributor.author | Feng, YY | en_US |
dc.contributor.author | Huang, JS | en_US |
dc.contributor.author | Shen, PW | en_US |
dc.date.accessioned | 2012-10-08T03:17:59Z | - |
dc.date.available | 2012-10-08T03:17:59Z | - |
dc.date.issued | 1997 | en_US |
dc.identifier.citation | Chemical Journal Of Chinese Universities, 1997, v. 18 n. 3, p. 357-359 | en_US |
dc.identifier.citation | 高等學校化學學报, 1997, v. 18 n. 3, p. 357-359 | - |
dc.identifier.issn | 0251-0790 | en_US |
dc.identifier.uri | http://hdl.handle.net/10722/168361 | - |
dc.description.abstract | A series of bis(amine) iron( II ) porphyrin Fe( II ) TPP(NH 2R) 2 complexes (NH 2R = PhNH 2, C 6H 11NH 2, n-BuNH 2, PhCH 2NH 2, NHMe 2; TPP = dianion of wwo-tetraphenylporphyrin ) were prepared by the reduction of Fe ( II ) porphyrins with the corresponding amine in an antiformin system in air as well as by the sodium borohydride reduction method, respectively. The complexes were charaterized by UV-Vis, IR and elementary analysis, and some important properties of them were discussed. | en_US |
dc.description.abstract | 已報道合成的二價鐵葉琳配合物主要集中在毗陡、咪唑、NO等配體上.有機胺雖然是配位化學中一類極為經典的配體,但合成金屬葉琳胺類配合物的報道卻為數甚少,據我們所知,僅限於Ru[1]、Rh[3]、Os[3]等配合物.迄今還未見合成鐵(Ⅱ)卟啉胺類的報道.本文通過引入強氧化劑安替福民, 實現了在含水含氧體系中合成2價鐵葉琳胺配合物, 為2價鐵葉琳配合物的合成開闢了一條新的途徑 | - |
dc.language | chi | en_US |
dc.publisher | Editorial office of Chemical Journal of Chinese Universities(高等學校化學學報編輯部). The Journal's web site is located at http://www.cjcu.jlu.edu.cn/ | en_US |
dc.relation.ispartof | Chemical Journal of Chinese Universities | en_US |
dc.relation.ispartof | 高等學校化學學报 | - |
dc.subject | Amine (胺) | en_US |
dc.subject | Bis(Amine)Iron(II) Porphyrin (鐵(Ⅱ)卟啉二胺) | en_US |
dc.subject | Synthesis (合成) | en_US |
dc.title | Synthesis and characterization of bis(amine) Iron (II) porphyrins | en_US |
dc.title | 鐵(Ⅱ)卟啉二胺配合物的合成和表征 | - |
dc.type | Article | en_US |
dc.identifier.email | Huang, JS:jshuang@hkucc.hku.hk | en_US |
dc.identifier.authority | Huang, JS=rp00709 | en_US |
dc.description.nature | link_to_subscribed_fulltext | en_US |
dc.identifier.scopus | eid_2-s2.0-6044236971 | en_US |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-6044236971&selection=ref&src=s&origin=recordpage | en_US |
dc.identifier.volume | 18 | en_US |
dc.identifier.issue | 3 | en_US |
dc.identifier.spage | 357 | en_US |
dc.identifier.epage | 359 | en_US |
dc.publisher.place | China | en_US |
dc.identifier.scopusauthorid | Zhong, XH=7202160428 | en_US |
dc.identifier.scopusauthorid | Feng, YY=55184206700 | en_US |
dc.identifier.scopusauthorid | Huang, JS=7407192639 | en_US |
dc.identifier.scopusauthorid | Shen, PW=7201767682 | en_US |
dc.customcontrol.immutable | csl 130729 | - |
dc.identifier.issnl | 0251-0790 | - |