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Article: Synthesis and characterization of bis(amine) Iron (II) porphyrins

TitleSynthesis and characterization of bis(amine) Iron (II) porphyrins
鐵(Ⅱ)卟啉二胺配合物的合成和表征
Authors
KeywordsAmine (胺)
Bis(Amine)Iron(II) Porphyrin (鐵(Ⅱ)卟啉二胺)
Synthesis (合成)
Issue Date1997
PublisherEditorial office of Chemical Journal of Chinese Universities(高等學校化學學報編輯部). The Journal's web site is located at http://www.cjcu.jlu.edu.cn/
Citation
Chemical Journal Of Chinese Universities, 1997, v. 18 n. 3, p. 357-359 How to Cite?
高等學校化學學报, 1997, v. 18 n. 3, p. 357-359 How to Cite?
AbstractA series of bis(amine) iron( II ) porphyrin Fe( II ) TPP(NH 2R) 2 complexes (NH 2R = PhNH 2, C 6H 11NH 2, n-BuNH 2, PhCH 2NH 2, NHMe 2; TPP = dianion of wwo-tetraphenylporphyrin ) were prepared by the reduction of Fe ( II ) porphyrins with the corresponding amine in an antiformin system in air as well as by the sodium borohydride reduction method, respectively. The complexes were charaterized by UV-Vis, IR and elementary analysis, and some important properties of them were discussed.
已報道合成的二價鐵葉琳配合物主要集中在毗陡、咪唑、NO等配體上.有機胺雖然是配位化學中一類極為經典的配體,但合成金屬葉琳胺類配合物的報道卻為數甚少,據我們所知,僅限於Ru[1]、Rh[3]、Os[3]等配合物.迄今還未見合成鐵(Ⅱ)卟啉胺類的報道.本文通過引入強氧化劑安替福民, 實現了在含水含氧體系中合成2價鐵葉琳胺配合物, 為2價鐵葉琳配合物的合成開闢了一條新的途徑
Persistent Identifierhttp://hdl.handle.net/10722/168361
ISSN
2015 Impact Factor: 0.791
2015 SCImago Journal Rankings: 0.211
References

 

DC FieldValueLanguage
dc.contributor.authorZhong, XHen_US
dc.contributor.authorFeng, YYen_US
dc.contributor.authorHuang, JSen_US
dc.contributor.authorShen, PWen_US
dc.date.accessioned2012-10-08T03:17:59Z-
dc.date.available2012-10-08T03:17:59Z-
dc.date.issued1997en_US
dc.identifier.citationChemical Journal Of Chinese Universities, 1997, v. 18 n. 3, p. 357-359en_US
dc.identifier.citation高等學校化學學报, 1997, v. 18 n. 3, p. 357-359-
dc.identifier.issn0251-0790en_US
dc.identifier.urihttp://hdl.handle.net/10722/168361-
dc.description.abstractA series of bis(amine) iron( II ) porphyrin Fe( II ) TPP(NH 2R) 2 complexes (NH 2R = PhNH 2, C 6H 11NH 2, n-BuNH 2, PhCH 2NH 2, NHMe 2; TPP = dianion of wwo-tetraphenylporphyrin ) were prepared by the reduction of Fe ( II ) porphyrins with the corresponding amine in an antiformin system in air as well as by the sodium borohydride reduction method, respectively. The complexes were charaterized by UV-Vis, IR and elementary analysis, and some important properties of them were discussed.en_US
dc.description.abstract已報道合成的二價鐵葉琳配合物主要集中在毗陡、咪唑、NO等配體上.有機胺雖然是配位化學中一類極為經典的配體,但合成金屬葉琳胺類配合物的報道卻為數甚少,據我們所知,僅限於Ru[1]、Rh[3]、Os[3]等配合物.迄今還未見合成鐵(Ⅱ)卟啉胺類的報道.本文通過引入強氧化劑安替福民, 實現了在含水含氧體系中合成2價鐵葉琳胺配合物, 為2價鐵葉琳配合物的合成開闢了一條新的途徑-
dc.languagechien_US
dc.publisherEditorial office of Chemical Journal of Chinese Universities(高等學校化學學報編輯部). The Journal's web site is located at http://www.cjcu.jlu.edu.cn/en_US
dc.relation.ispartofChemical Journal of Chinese Universitiesen_US
dc.relation.ispartof高等學校化學學报-
dc.subjectAmine (胺)en_US
dc.subjectBis(Amine)Iron(II) Porphyrin (鐵(Ⅱ)卟啉二胺)en_US
dc.subjectSynthesis (合成)en_US
dc.titleSynthesis and characterization of bis(amine) Iron (II) porphyrinsen_US
dc.title鐵(Ⅱ)卟啉二胺配合物的合成和表征-
dc.typeArticleen_US
dc.identifier.emailHuang, JS:jshuang@hkucc.hku.hken_US
dc.identifier.authorityHuang, JS=rp00709en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-6044236971en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-6044236971&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume18en_US
dc.identifier.issue3en_US
dc.identifier.spage357en_US
dc.identifier.epage359en_US
dc.publisher.placeChinaen_US
dc.identifier.scopusauthoridZhong, XH=7202160428en_US
dc.identifier.scopusauthoridFeng, YY=55184206700en_US
dc.identifier.scopusauthoridHuang, JS=7407192639en_US
dc.identifier.scopusauthoridShen, PW=7201767682en_US
dc.customcontrol.immutablecsl 130729-

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