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Article: Structural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III)

TitleStructural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III)
Authors
Issue Date1981
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1981 n. 8, p. 1697-1700 How to Cite?
AbstractA series of osmium(III) amine complexes of the types trans-[OsLCl2]+ [L = L1, bis(ethane-1,2-diamine); L2, 3,7-diazanonane-1,9-diamine; L3, 4,7-diazadecane-1,10-diamine; L4, 1,4,8,11-tetra-azacyclotetradecane; or L5, 1,4,8,12-tetra-azacyclopentadecane], trans-[OsLBr2]+ (L = L3, L4, or L5), and trans-[OsL3I2]+ has been prepared and characterized. All these complexes are low-spin monomeric species. The general synthetic methods and the electronic and i.r. absorption spectra of these complexes are discussed.
Persistent Identifierhttp://hdl.handle.net/10722/168263
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorPoon, CKen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorTang, TWen_US
dc.date.accessioned2012-10-08T03:16:47Z-
dc.date.available2012-10-08T03:16:47Z-
dc.date.issued1981en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1981 n. 8, p. 1697-1700en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168263-
dc.description.abstractA series of osmium(III) amine complexes of the types trans-[OsLCl2]+ [L = L1, bis(ethane-1,2-diamine); L2, 3,7-diazanonane-1,9-diamine; L3, 4,7-diazadecane-1,10-diamine; L4, 1,4,8,11-tetra-azacyclotetradecane; or L5, 1,4,8,12-tetra-azacyclopentadecane], trans-[OsLBr2]+ (L = L3, L4, or L5), and trans-[OsL3I2]+ has been prepared and characterized. All these complexes are low-spin monomeric species. The general synthetic methods and the electronic and i.r. absorption spectra of these complexes are discussed.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleStructural and mechanistic studies of co-ordination compounds. Part 30. Synthesis and characterization of some octahedral halogenoamine complexes of osmium(III)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9810001697en_US
dc.identifier.scopuseid_2-s2.0-37049106107en_US
dc.identifier.issue8en_US
dc.identifier.spage1697en_US
dc.identifier.epage1700en_US
dc.identifier.isiWOS:A1981MC94100006-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridTang, TW=15222800500en_US

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