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Article: Structural and mechanistic studies of co-ordination compounds. Part 25. Synthesis and characterization of some octahedral halogeno-amine and -thioether complexes of ruthenium-(II) and -(III)

TitleStructural and mechanistic studies of co-ordination compounds. Part 25. Synthesis and characterization of some octahedral halogeno-amine and -thioether complexes of ruthenium-(II) and -(III)
Authors
Issue Date1980
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1980 n. 5, p. 756-762 How to Cite?
AbstractThe published methods for the syntheses of trans-[RuLCl2]+ [L = L1, bis(ethane-1,2-diamine); L4, 3,7-diazanonane-1,9-diamine; or L7, 1,4,8,11-tetra-azacyclotetradecane] have been modified. The modified method is highly efficient and reproducible and it has been employed to prepare other trans-[RuLCl2]+ complexes [L = L2, bis(propane-1,3-diamine); L3, bis(NN′-dimethylethane-1,2-diamine); L5, 4,7-diazadecane-1,10-diamine; or L6, 4,8-diazaundecane-1,11-diamine]. Other dihalogeno-complexes, trans-[RuLBr2]+ (L = L1, L2, L4, or L7) and trans-[RuLI2]+ (L = L1 or L4), have been prepared form their corresponding dichloro-complexes through the reactive ruthenium(II) intermediates. Mixed halogeno-complexes of the type trans-[RuL1(X)Y]+ [(X)Y = (Cl) Br, (Cl)l, or (l)Br] have been prepared by metathetical procedures. Meanwhile, some macrocyclic quadridentate thioether complexes trans-[RuLCl2]·2H2O (L = L8, 1,4,8,11-tetrathiacyclotetradecane; or L9, 3,6,10,13-tetrathiabicyclo[13.4.0]nona-1,16,18-triene) and trans-[RuL8Cl2][ClO4]·H2O have also been synthesized. All these complexes are low-spin monomeric species. The electronic and i.r. absorption spectra of these complexes are discussed.
Persistent Identifierhttp://hdl.handle.net/10722/168261
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorPoon, CKen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:16:47Z-
dc.date.available2012-10-08T03:16:47Z-
dc.date.issued1980en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1980 n. 5, p. 756-762en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168261-
dc.description.abstractThe published methods for the syntheses of trans-[RuLCl2]+ [L = L1, bis(ethane-1,2-diamine); L4, 3,7-diazanonane-1,9-diamine; or L7, 1,4,8,11-tetra-azacyclotetradecane] have been modified. The modified method is highly efficient and reproducible and it has been employed to prepare other trans-[RuLCl2]+ complexes [L = L2, bis(propane-1,3-diamine); L3, bis(NN′-dimethylethane-1,2-diamine); L5, 4,7-diazadecane-1,10-diamine; or L6, 4,8-diazaundecane-1,11-diamine]. Other dihalogeno-complexes, trans-[RuLBr2]+ (L = L1, L2, L4, or L7) and trans-[RuLI2]+ (L = L1 or L4), have been prepared form their corresponding dichloro-complexes through the reactive ruthenium(II) intermediates. Mixed halogeno-complexes of the type trans-[RuL1(X)Y]+ [(X)Y = (Cl) Br, (Cl)l, or (l)Br] have been prepared by metathetical procedures. Meanwhile, some macrocyclic quadridentate thioether complexes trans-[RuLCl2]·2H2O (L = L8, 1,4,8,11-tetrathiacyclotetradecane; or L9, 3,6,10,13-tetrathiabicyclo[13.4.0]nona-1,16,18-triene) and trans-[RuL8Cl2][ClO4]·H2O have also been synthesized. All these complexes are low-spin monomeric species. The electronic and i.r. absorption spectra of these complexes are discussed.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleStructural and mechanistic studies of co-ordination compounds. Part 25. Synthesis and characterization of some octahedral halogeno-amine and -thioether complexes of ruthenium-(II) and -(III)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9800000756en_US
dc.identifier.scopuseid_2-s2.0-37049100246en_US
dc.identifier.issue5en_US
dc.identifier.spage756en_US
dc.identifier.epage762en_US
dc.identifier.isiWOS:A1980JS44600011-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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