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Article: Structural and mechanistic studies of co-ordination compounds. Part 26. Synthesis and characterization of some octahedral complexes of ruthenium-(II) and -(III) with macrocyclic quadridentate thioethers

TitleStructural and mechanistic studies of co-ordination compounds. Part 26. Synthesis and characterization of some octahedral complexes of ruthenium-(II) and -(III) with macrocyclic quadridentate thioethers
Authors
Issue Date1981
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1981 n. 2, p. 495-500 How to Cite?
AbstractA series of ruthenium-(II) and -(III) complexes of the macrocyclic quadridentate thioethers 1,4,8,11-tetrathiacyclotetradecane (L1) and 1,4,7,10-tetrathiacyclotridecane (L2) has been prepared and characterized. Complexes containing the 14-membered ring, L1, viz. trans-[RuL1X2]+ (X = Cl or Br), trans-[RuL1X2] (X = Cl, Br, I, NCS, N3, or NO2), and trans-[RuL1X(OH2)]+ (X = Cl or Br), have the two remaining unidentate ligands trans to each other. However, the 13-membered ring, L2, co-ordinates to the central metal ion in a folded manner to give cis-[RuL2Cl2]+, cis-[RuL2X2] (X = Cl, Br, I, NCS, NO2, or N3), and cis-[RuL2Cl(OH2)]+. All the ruthenium(III) complexes are low spin and the ruthenium(II) complexes diamagnetic. They are all monomeric species. The electronic and i.r. absorption spectra of these complexes are discussed.
Persistent Identifierhttp://hdl.handle.net/10722/168259
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorPoon, CKen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:16:46Z-
dc.date.available2012-10-08T03:16:46Z-
dc.date.issued1981en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1981 n. 2, p. 495-500en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168259-
dc.description.abstractA series of ruthenium-(II) and -(III) complexes of the macrocyclic quadridentate thioethers 1,4,8,11-tetrathiacyclotetradecane (L1) and 1,4,7,10-tetrathiacyclotridecane (L2) has been prepared and characterized. Complexes containing the 14-membered ring, L1, viz. trans-[RuL1X2]+ (X = Cl or Br), trans-[RuL1X2] (X = Cl, Br, I, NCS, N3, or NO2), and trans-[RuL1X(OH2)]+ (X = Cl or Br), have the two remaining unidentate ligands trans to each other. However, the 13-membered ring, L2, co-ordinates to the central metal ion in a folded manner to give cis-[RuL2Cl2]+, cis-[RuL2X2] (X = Cl, Br, I, NCS, NO2, or N3), and cis-[RuL2Cl(OH2)]+. All the ruthenium(III) complexes are low spin and the ruthenium(II) complexes diamagnetic. They are all monomeric species. The electronic and i.r. absorption spectra of these complexes are discussed.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titleStructural and mechanistic studies of co-ordination compounds. Part 26. Synthesis and characterization of some octahedral complexes of ruthenium-(II) and -(III) with macrocyclic quadridentate thioethersen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9810000495en_US
dc.identifier.scopuseid_2-s2.0-37049098577en_US
dc.identifier.issue2en_US
dc.identifier.spage495en_US
dc.identifier.epage500en_US
dc.identifier.isiWOS:A1981LC35400030-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridPoon, CK=7202673504en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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