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Article: Preparation and crystal structure of a seven-co-ordinated oxotungsten(IV) complex of 2,2′:6′,2″:6″,2‴-quaterpyridine

TitlePreparation and crystal structure of a seven-co-ordinated oxotungsten(IV) complex of 2,2′:6′,2″:6″,2‴-quaterpyridine
Authors
Issue Date1993
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/dalton
Citation
Journal Of The Chemical Society, Dalton Transactions, 1993 n. 23, p. 3515-3517 How to Cite?
AbstractThe reaction of [WOCl2(PMe2Ph)3] with 2,2′:6′,2″:6″,2‴-quaterpyridine (L) in ethanol gave [WO(PMe2Ph)2L]2+ isolated as a BPh4 - salt. X-Ray diffraction analysis revealed that the complex cation adopts a distorted pentagonal-bipyramidal structure with the W≡O distance being 1.696(9) Å. The spectroscopic properties and electrochemistry of this tungsten complex have been investigated.
Persistent Identifierhttp://hdl.handle.net/10722/168207
ISSN
2002 Impact Factor: 3.023
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorYang, SMen_US
dc.contributor.authorCheung, KKen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:16:16Z-
dc.date.available2012-10-08T03:16:16Z-
dc.date.issued1993en_US
dc.identifier.citationJournal Of The Chemical Society, Dalton Transactions, 1993 n. 23, p. 3515-3517en_US
dc.identifier.issn1472-7773en_US
dc.identifier.urihttp://hdl.handle.net/10722/168207-
dc.description.abstractThe reaction of [WOCl2(PMe2Ph)3] with 2,2′:6′,2″:6″,2‴-quaterpyridine (L) in ethanol gave [WO(PMe2Ph)2L]2+ isolated as a BPh4 - salt. X-Ray diffraction analysis revealed that the complex cation adopts a distorted pentagonal-bipyramidal structure with the W≡O distance being 1.696(9) Å. The spectroscopic properties and electrochemistry of this tungsten complex have been investigated.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/daltonen_US
dc.relation.ispartofJournal of the Chemical Society, Dalton Transactionsen_US
dc.titlePreparation and crystal structure of a seven-co-ordinated oxotungsten(IV) complex of 2,2′:6′,2″:6″,2‴-quaterpyridineen_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/DT9930003515en_US
dc.identifier.scopuseid_2-s2.0-37049075906en_US
dc.identifier.issue23en_US
dc.identifier.spage3515en_US
dc.identifier.epage3517en_US
dc.identifier.isiWOS:A1993ML26000011-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridYang, SM=7408521494en_US
dc.identifier.scopusauthoridCheung, KK=7402406613en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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