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Article: Novel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au2(dmb)(CN)2 (dmb = 1,8-di-isocyano-p-menthane)

TitleNovel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au2(dmb)(CN)2 (dmb = 1,8-di-isocyano-p-menthane)
Authors
Issue Date1989
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1989 n. 4, p. 243-244 How to Cite?
AbstractReaction of K[AuCl4] with dmb (1,8-di-isocyano-p-menthane) in boiling ethanol yielded Au2(dmb)(CN)2 with an intramolecular Au-Au separation of 3.536 Å excitation of Au 2(dmb)(CN)2 in fluid solution and in the solid state leads to photoluminescence (λmax. ∼468 nm, τ0 0.13 μs in degassed CH2Cl2).
Persistent Identifierhttp://hdl.handle.net/10722/168173
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_HK
dc.contributor.authorWong, WTen_HK
dc.contributor.authorLai, TFen_HK
dc.contributor.authorKwong, HLen_HK
dc.date.accessioned2012-10-08T03:15:57Z-
dc.date.available2012-10-08T03:15:57Z-
dc.date.issued1989en_HK
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1989 n. 4, p. 243-244en_HK
dc.identifier.issn0022-4936en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168173-
dc.description.abstractReaction of K[AuCl4] with dmb (1,8-di-isocyano-p-menthane) in boiling ethanol yielded Au2(dmb)(CN)2 with an intramolecular Au-Au separation of 3.536 Å excitation of Au 2(dmb)(CN)2 in fluid solution and in the solid state leads to photoluminescence (λmax. ∼468 nm, τ0 0.13 μs in degassed CH2Cl2).en_HK
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_HK
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_HK
dc.titleNovel luminescent binuclear gold(I) isocyanide complexes. Synthesis, spectroscopy, and X-ray crystal structure of Au2(dmb)(CN)2 (dmb = 1,8-di-isocyano-p-menthane)en_HK
dc.typeArticleen_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.emailWong, WT: wtwong@hku.hken_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.identifier.authorityWong, WT=rp00811en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39890000243en_HK
dc.identifier.scopuseid_2-s2.0-37049069342en_HK
dc.identifier.issue4en_HK
dc.identifier.spage243en_HK
dc.identifier.epage244en_HK
dc.identifier.isiWOS:A1989T611800022-
dc.publisher.placeUnited Kingdomen_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridWong, WT=7403973084en_HK
dc.identifier.scopusauthoridLai, TF=7202203523en_HK
dc.identifier.scopusauthoridKwong, HL=35569416300en_HK

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