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Article: Metal-oxo photo-oxidants: Photochemical oxidation of hydrocarbons by trans-dioxo complexes of ruthenium(VI) and osmium(VI)

TitleMetal-oxo photo-oxidants: Photochemical oxidation of hydrocarbons by trans-dioxo complexes of ruthenium(VI) and osmium(VI)
Authors
Yam, VWWChe, CMTang, WT
Issue Date1988
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Journal Of The Chemical Society, Chemical Communications, 1988 n. 2, p. 100-102 How to Cite?
DOI: http://dx.doi.org/10.1039/C39880000100
AbstractThe synthesis of trans-[RuVI(L)(O)2]Y2 (Y = PF6 or ClO4) and trans-[RuIV(L)(NCO)(O)] ClO4 {L = meso-1,2,6,10,11-pentamethyl-2,6,10-triaza[11](2,6) pyridinophane} is described; irradiation of trans-[RuVI(L)(O) 2]2+ and [OsVI(CN)4(O) 2]2- (λ > 330 nm) in presence of organic substrates yielded the corresponding oxidized organic products indicating that the (dxy)1(dπ*)1 excited states of RuVI- and OsVI-oxo complexes are reactive towards epoxidation of alkenes and to oxidation of C-H bonds.
Persistent Identifierhttp://hdl.handle.net/10722/168170
ISSN
0022-4936
ISI Accession Number ID
WOS:A1988L906500015

 

DC FieldValueLanguage
dc.contributor.authorYam, VWWen_US
dc.contributor.authorChe, CMen_US
dc.contributor.authorTang, WTen_US
dc.date.accessioned2012-10-08T03:15:56Z-
dc.date.available2012-10-08T03:15:56Z-
dc.date.issued1988en_US
dc.identifier.citationJournal Of The Chemical Society, Chemical Communications, 1988 n. 2, p. 100-102en_US
dc.identifier.issn0022-4936en_US
dc.identifier.urihttp://hdl.handle.net/10722/168170-
dc.description.abstractThe synthesis of trans-[RuVI(L)(O)2]Y2 (Y = PF6 or ClO4) and trans-[RuIV(L)(NCO)(O)] ClO4 {L = meso-1,2,6,10,11-pentamethyl-2,6,10-triaza[11](2,6) pyridinophane} is described; irradiation of trans-[RuVI(L)(O) 2]2+ and [OsVI(CN)4(O) 2]2- (λ > 330 nm) in presence of organic substrates yielded the corresponding oxidized organic products indicating that the (dxy)1(dπ*)1 excited states of RuVI- and OsVI-oxo complexes are reactive towards epoxidation of alkenes and to oxidation of C-H bonds.en_US
dc.languageengen_US
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.aspen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.titleMetal-oxo photo-oxidants: Photochemical oxidation of hydrocarbons by trans-dioxo complexes of ruthenium(VI) and osmium(VI)en_US
dc.typeArticleen_US
dc.identifier.emailYam, VWW:wwyam@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityYam, VWW=rp00822en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/C39880000100en_US
dc.identifier.scopuseid_2-s2.0-37049068682en_US
dc.identifier.issue2en_US
dc.identifier.spage100en_US
dc.identifier.epage102en_US
dc.identifier.isiWOS:A1988L906500015-
dc.publisher.placeUnited Kingdomen_US
dc.identifier.scopusauthoridYam, VWW=18539304700en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridTang, WT=15121154000en_US
dc.identifier.issnl0022-4936-

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