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Article: Multiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networks

TitleMultiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networks
Authors
Issue Date2007
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2007, v. 46 n. 12, p. 4844-4849 How to Cite?
AbstractWe introduce the 1,2,3-tris(organylthiophenyl) group as a symmetrical, multidentate chelation link for building coordination networks. For this, zinc(II) 5,10,15,20-tetrakis[3′,4′,5′-tris(methylthio)phenyl] porphyrin was synthesized and integrated into a two-dimensional network via coordination with BiBr 3. The coordination link exhibits an unusually complex bonding pattern, involving six S atoms from two neighboring ligands that form multiple Bi-S interactions (distances ranging from 3.08 to 3.63 Å) with a dimerlike unit of Bi 2Br 6. The electronic interaction between the porphyrin center and the Bi 2Br 6 block was illustrated by the diffuse-reflectance spectrum of the network compound, in which a modest red-shifted feature at 1.8 eV was seen (while the Q-band absorption of the metalloporphyrin core continues to be dominant at 1.9 eV). © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168125
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, Ken_HK
dc.contributor.authorHuang, Gen_HK
dc.contributor.authorXu, Zen_HK
dc.contributor.authorZhang, Men_HK
dc.contributor.authorZeller, Men_HK
dc.contributor.authorHunter, ADen_HK
dc.contributor.authorChui, SSYen_HK
dc.contributor.authorChe, CMen_HK
dc.contributor.authorWong, WYen_HK
dc.date.accessioned2012-10-08T03:15:24Z-
dc.date.available2012-10-08T03:15:24Z-
dc.date.issued2007en_HK
dc.identifier.citationInorganic Chemistry, 2007, v. 46 n. 12, p. 4844-4849en_HK
dc.identifier.issn0020-1669en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168125-
dc.description.abstractWe introduce the 1,2,3-tris(organylthiophenyl) group as a symmetrical, multidentate chelation link for building coordination networks. For this, zinc(II) 5,10,15,20-tetrakis[3′,4′,5′-tris(methylthio)phenyl] porphyrin was synthesized and integrated into a two-dimensional network via coordination with BiBr 3. The coordination link exhibits an unusually complex bonding pattern, involving six S atoms from two neighboring ligands that form multiple Bi-S interactions (distances ranging from 3.08 to 3.63 Å) with a dimerlike unit of Bi 2Br 6. The electronic interaction between the porphyrin center and the Bi 2Br 6 block was illustrated by the diffuse-reflectance spectrum of the network compound, in which a modest red-shifted feature at 1.8 eV was seen (while the Q-band absorption of the metalloporphyrin core continues to be dominant at 1.9 eV). © 2007 American Chemical Society.en_HK
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_HK
dc.relation.ispartofInorganic Chemistryen_HK
dc.subject.meshBismuth - Chemistryen_US
dc.subject.meshLigandsen_US
dc.subject.meshMacromolecular Substances - Chemistryen_US
dc.subject.meshMetalloporphyrins - Chemistryen_US
dc.subject.meshSpectrum Analysisen_US
dc.subject.meshSulfides - Chemistryen_US
dc.titleMultiple bismuth(III)-thioether secondary interactions integrate metalloporphyrin ligands into functional networksen_HK
dc.typeArticleen_HK
dc.identifier.emailChui, SSY: chuissy@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityChui, SSY=rp00686en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic061711men_HK
dc.identifier.pmid17488068-
dc.identifier.scopuseid_2-s2.0-34347268820en_HK
dc.identifier.hkuros137045-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-34347268820&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume46en_HK
dc.identifier.issue12en_HK
dc.identifier.spage4844en_HK
dc.identifier.epage4849en_HK
dc.identifier.isiWOS:000246907800019-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLi, K=55487992100en_HK
dc.identifier.scopusauthoridHuang, G=36984730800en_HK
dc.identifier.scopusauthoridXu, Z=9843801700en_HK
dc.identifier.scopusauthoridZhang, M=36072753300en_HK
dc.identifier.scopusauthoridZeller, M=8518298000en_HK
dc.identifier.scopusauthoridHunter, AD=7402779700en_HK
dc.identifier.scopusauthoridChui, SSY=8297453100en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK
dc.identifier.scopusauthoridWong, WY=7403972153en_HK

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