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Article: Photochemical hydrogen atom transfer from aldehydes to binuclear platinum(II)

TitlePhotochemical hydrogen atom transfer from aldehydes to binuclear platinum(II)
Authors
Issue Date1988
PublisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1011-372X
Citation
Catalysis Letters, 1988, v. 1 n. 8-9, p. 261-264 How to Cite?
AbstractThe phosphorescence of the triplet excited state (3Pt2 *) of a binuclear platinum(II) complex, Pt2(P2O5H2)4 4-, is quenched by acetaldehyde and propionaldehyde with second-order rate constants of 5×105 and 2×105 M-1 s-1, respectively, in methanol at room temperature. Flash photolysis experiments establish that the reaction of3Pt2 * with RCHO occurs by hydrogen atom transfer,3Pt2 *+RCHO→Pt2H+RCO. The experiments also indicate that the Pt2H intermediate reduces aldehydes to alcohols. © 1988 J.C. Baltzer A.G. Scientific Publishing Company.
Persistent Identifierhttp://hdl.handle.net/10722/168119
ISSN
2015 Impact Factor: 2.294
2015 SCImago Journal Rankings: 0.777

 

DC FieldValueLanguage
dc.contributor.authorChe, CMen_US
dc.contributor.authorKwong, HLen_US
dc.contributor.authorCho, KCen_US
dc.contributor.authorHarvey, PDen_US
dc.contributor.authorGray, HBen_US
dc.date.accessioned2012-10-08T03:15:18Z-
dc.date.available2012-10-08T03:15:18Z-
dc.date.issued1988en_US
dc.identifier.citationCatalysis Letters, 1988, v. 1 n. 8-9, p. 261-264en_US
dc.identifier.issn1011-372Xen_US
dc.identifier.urihttp://hdl.handle.net/10722/168119-
dc.description.abstractThe phosphorescence of the triplet excited state (3Pt2 *) of a binuclear platinum(II) complex, Pt2(P2O5H2)4 4-, is quenched by acetaldehyde and propionaldehyde with second-order rate constants of 5×105 and 2×105 M-1 s-1, respectively, in methanol at room temperature. Flash photolysis experiments establish that the reaction of3Pt2 * with RCHO occurs by hydrogen atom transfer,3Pt2 *+RCHO→Pt2H+RCO. The experiments also indicate that the Pt2H intermediate reduces aldehydes to alcohols. © 1988 J.C. Baltzer A.G. Scientific Publishing Company.en_US
dc.languageengen_US
dc.publisherSpringer New York LLC. The Journal's web site is located at http://springerlink.metapress.com/openurl.asp?genre=journal&issn=1011-372Xen_US
dc.relation.ispartofCatalysis Lettersen_US
dc.titlePhotochemical hydrogen atom transfer from aldehydes to binuclear platinum(II)en_US
dc.typeArticleen_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1007/BF00765304en_US
dc.identifier.scopuseid_2-s2.0-34250097281en_US
dc.identifier.volume1en_US
dc.identifier.issue8-9en_US
dc.identifier.spage261en_US
dc.identifier.epage264en_US
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US
dc.identifier.scopusauthoridKwong, HL=35569416300en_US
dc.identifier.scopusauthoridCho, KC=15129672200en_US
dc.identifier.scopusauthoridHarvey, PD=7401431908en_US
dc.identifier.scopusauthoridGray, HB=36047602600en_US

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