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Article: Time-resolved resonance Raman study of the reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide

TitleTime-resolved resonance Raman study of the reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide
Authors
Issue Date2007
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2007, v. 111 n. 8, p. 1441-1451 How to Cite?
AbstractA time-resolved resonance Raman investigation of the reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide in a mixed aqueous solvent is presented. The reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide in the mixed aqueous solution generates two new species on the microsecond time scale. One of these species is identified as 2,2′-azobisfluorene, and the other species is tentatively assigned to a 1,4-bis-(2,2′-fluorenyl)- tetrazadiene cation intermediate. The structure and properties of these two species are briefly discussed. The reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide is also briefly compared to that of the 2-fluorenylnitrenium ion reactions with guanosine and water. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168098
ISSN
2015 Impact Factor: 2.883
2015 SCImago Journal Rankings: 1.231
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorXue, Jen_US
dc.contributor.authorGuo, Zen_US
dc.contributor.authorChan, PYen_US
dc.contributor.authorChu, LMen_US
dc.contributor.authorBut, TYSen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:15:04Z-
dc.date.available2012-10-08T03:15:04Z-
dc.date.issued2007en_US
dc.identifier.citationJournal Of Physical Chemistry A, 2007, v. 111 n. 8, p. 1441-1451en_US
dc.identifier.issn1089-5639en_US
dc.identifier.urihttp://hdl.handle.net/10722/168098-
dc.description.abstractA time-resolved resonance Raman investigation of the reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide in a mixed aqueous solvent is presented. The reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide in the mixed aqueous solution generates two new species on the microsecond time scale. One of these species is identified as 2,2′-azobisfluorene, and the other species is tentatively assigned to a 1,4-bis-(2,2′-fluorenyl)- tetrazadiene cation intermediate. The structure and properties of these two species are briefly discussed. The reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazide is also briefly compared to that of the 2-fluorenylnitrenium ion reactions with guanosine and water. © 2007 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_US
dc.relation.ispartofJournal of Physical Chemistry Aen_US
dc.subject.meshAzides - Chemistryen_US
dc.subject.meshCations, Monovalenten_US
dc.subject.meshFluorenes - Chemistryen_US
dc.subject.meshModels, Chemicalen_US
dc.subject.meshReference Standardsen_US
dc.subject.meshSensitivity And Specificityen_US
dc.subject.meshSolutions - Chemistryen_US
dc.subject.meshSpectrum Analysis, Raman - Methods - Standardsen_US
dc.subject.meshTime Factorsen_US
dc.titleTime-resolved resonance Raman study of the reaction of the 2-fluorenylnitrenium ion with 2-fluorenylazideen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/jp066699yen_US
dc.identifier.pmid17269755-
dc.identifier.scopuseid_2-s2.0-33947366472en_US
dc.identifier.hkuros133767-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33947366472&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume111en_US
dc.identifier.issue8en_US
dc.identifier.spage1441en_US
dc.identifier.epage1451en_US
dc.identifier.isiWOS:000244348100008-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridXue, J=23007272500en_US
dc.identifier.scopusauthoridGuo, Z=36554069300en_US
dc.identifier.scopusauthoridChan, PY=7403497922en_US
dc.identifier.scopusauthoridChu, LM=8595123000en_US
dc.identifier.scopusauthoridBut, TYS=8774303500en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US

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