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Article: Synthesis, structure and spectroscopic properties of [Cu3(μ-dpnapy)3-(CH3CN)][ClO4]3·CH3CN(dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom array

TitleSynthesis, structure and spectroscopic properties of [Cu3(μ-dpnapy)3-(CH3CN)][ClO4]3·CH3CN(dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom array
Authors
Issue Date1998
Citation
Journal Of The Chemical Society - Dalton Transactions, 1998 n. 17, p. 2867-2871 How to Cite?
AbstractThe co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I has been examined. Reaction of [Cu(CH 3CN) 4][ClO 4] with dpnapy in CH 3CN afforded [Cu 3(μ-dpnapy) 3(CH 3CN)][ClO 4] 3 1[ClO 4] 3. The crystal structure of 1[ClO 4] 3·CH 3CN reveals a linear Cu-Cu-Cu array with both trigonal and tetrahedral co-ordination modes for the copper atoms. The intramolecular Cu-Cu distances of 2.449(2) and 2.721(2) Å suggest that only two of the copper atoms have a bonding interaction. Complex 1 reacts with triphenylphosphine (PPh 3) and 2,2′-bipyridine (bpy) to give [Cu(bpy)(dpnapy) 2][ClO 4] 2[ClO 4] and [Cu 2(μ-dpnapy) 3][ClO 4] 2 3[ClO 4] 2, respectively. Spectroscopic properties of the complexes have been examined.
Persistent Identifierhttp://hdl.handle.net/10722/168051
ISSN
1999 Impact Factor: 2.31
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorChan, WHen_US
dc.contributor.authorPeng, SMen_US
dc.contributor.authorChe, CMen_US
dc.date.accessioned2012-10-08T03:14:34Z-
dc.date.available2012-10-08T03:14:34Z-
dc.date.issued1998en_US
dc.identifier.citationJournal Of The Chemical Society - Dalton Transactions, 1998 n. 17, p. 2867-2871en_US
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/10722/168051-
dc.description.abstractThe co-ordination chemistry of 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (dpnapy) with Cu I has been examined. Reaction of [Cu(CH 3CN) 4][ClO 4] with dpnapy in CH 3CN afforded [Cu 3(μ-dpnapy) 3(CH 3CN)][ClO 4] 3 1[ClO 4] 3. The crystal structure of 1[ClO 4] 3·CH 3CN reveals a linear Cu-Cu-Cu array with both trigonal and tetrahedral co-ordination modes for the copper atoms. The intramolecular Cu-Cu distances of 2.449(2) and 2.721(2) Å suggest that only two of the copper atoms have a bonding interaction. Complex 1 reacts with triphenylphosphine (PPh 3) and 2,2′-bipyridine (bpy) to give [Cu(bpy)(dpnapy) 2][ClO 4] 2[ClO 4] and [Cu 2(μ-dpnapy) 3][ClO 4] 2 3[ClO 4] 2, respectively. Spectroscopic properties of the complexes have been examined.en_US
dc.languageengen_US
dc.relation.ispartofJournal of the Chemical Society - Dalton Transactionsen_US
dc.titleSynthesis, structure and spectroscopic properties of [Cu3(μ-dpnapy)3-(CH3CN)][ClO4]3·CH3CN(dpnapy = 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine) with a linear copper atom arrayen_US
dc.typeArticleen_US
dc.identifier.emailChan, WH:waichan@hku.hken_US
dc.identifier.emailChe, CM:cmche@hku.hken_US
dc.identifier.authorityChan, WH=rp00667en_US
dc.identifier.authorityChe, CM=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1039/A802279H-
dc.identifier.scopuseid_2-s2.0-33749099789en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33749099789&selection=ref&src=s&origin=recordpageen_US
dc.identifier.issue17en_US
dc.identifier.spage2867en_US
dc.identifier.epage2871en_US
dc.identifier.isiWOS:000075954300017-
dc.identifier.scopusauthoridChan, WH=13310083000en_US
dc.identifier.scopusauthoridPeng, SM=35464852200en_US
dc.identifier.scopusauthoridChe, CM=7102442791en_US

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