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Article: Self-assembly of a highly stable, topologically interesting metallamacrocycle by bridging gold(I) ions with pyridyl-2,6-diphenyl 2- and diphosphanes

TitleSelf-assembly of a highly stable, topologically interesting metallamacrocycle by bridging gold(I) ions with pyridyl-2,6-diphenyl 2- and diphosphanes
Authors
KeywordsAurophilicity
Gold
Metallacycles
Möbius strip
Structure elucidation
Issue Date2006
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/home
Citation
Angewandte Chemie - International Edition, 2006, v. 45 n. 28, p. 4663-4666 How to Cite?
Abstract(Figure Presented) A Möbius arrangement of the bonds directly attached to a metallamacrocycle was observed for the AuI complex [Au 3(CNC)(μ-Ph2PCH2PPh2) 2]+, which was self-assembled by treating the lithium salt of pyridyl-2,6-diphenyl2- (CNC) with [Au2Cl 2(μ-Ph2PCH2PPh2)]. The trinuclear AuI complex has intramolecular Au⋯Au and C-C⋯π interactions, exhibits a remarkable stability in solution, and is cytotoxic toward cancer cell lines. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/168030
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorKui, SCFen_HK
dc.contributor.authorHuang, JSen_HK
dc.contributor.authorSun, RWYen_HK
dc.contributor.authorZhu, Nen_HK
dc.contributor.authorChe, CMen_HK
dc.date.accessioned2012-10-08T03:14:20Z-
dc.date.available2012-10-08T03:14:20Z-
dc.date.issued2006en_HK
dc.identifier.citationAngewandte Chemie - International Edition, 2006, v. 45 n. 28, p. 4663-4666en_HK
dc.identifier.issn1433-7851en_HK
dc.identifier.urihttp://hdl.handle.net/10722/168030-
dc.description.abstract(Figure Presented) A Möbius arrangement of the bonds directly attached to a metallamacrocycle was observed for the AuI complex [Au 3(CNC)(μ-Ph2PCH2PPh2) 2]+, which was self-assembled by treating the lithium salt of pyridyl-2,6-diphenyl2- (CNC) with [Au2Cl 2(μ-Ph2PCH2PPh2)]. The trinuclear AuI complex has intramolecular Au⋯Au and C-C⋯π interactions, exhibits a remarkable stability in solution, and is cytotoxic toward cancer cell lines. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.en_HK
dc.languageengen_US
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www3.interscience.wiley.com/journal/26737/homeen_HK
dc.relation.ispartofAngewandte Chemie - International Editionen_HK
dc.subjectAurophilicityen_HK
dc.subjectGolden_HK
dc.subjectMetallacyclesen_HK
dc.subjectMöbius stripen_HK
dc.subjectStructure elucidationen_HK
dc.subject.meshGold - Chemistryen_US
dc.subject.meshMacrocyclic Compounds - Chemical Synthesisen_US
dc.subject.meshModels, Molecularen_US
dc.subject.meshMolecular Structureen_US
dc.subject.meshPhosphines - Chemistryen_US
dc.titleSelf-assembly of a highly stable, topologically interesting metallamacrocycle by bridging gold(I) ions with pyridyl-2,6-diphenyl 2- and diphosphanesen_HK
dc.typeArticleen_HK
dc.identifier.emailKui, SCF: stevenku@hku.hken_HK
dc.identifier.emailHuang, JS: jshuang@hku.hken_HK
dc.identifier.emailSun, RWY: rwysun@hku.hken_HK
dc.identifier.emailZhu, N: nzhu@hkucc.hku.hken_HK
dc.identifier.emailChe, CM: cmche@hku.hken_HK
dc.identifier.authorityKui, SCF=rp00715en_HK
dc.identifier.authorityHuang, JS=rp00709en_HK
dc.identifier.authoritySun, RWY=rp00781en_HK
dc.identifier.authorityZhu, N=rp00845en_HK
dc.identifier.authorityChe, CM=rp00670en_HK
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1002/anie.200600794en_HK
dc.identifier.pmid16791889-
dc.identifier.scopuseid_2-s2.0-33746322425en_HK
dc.identifier.hkuros121624-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33746322425&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume45en_HK
dc.identifier.issue28en_HK
dc.identifier.spage4663en_HK
dc.identifier.epage4666en_HK
dc.identifier.isiWOS:000239079900027-
dc.publisher.placeGermanyen_HK
dc.identifier.scopusauthoridKui, SCF=6506763660en_HK
dc.identifier.scopusauthoridHuang, JS=7407192639en_HK
dc.identifier.scopusauthoridSun, RWY=26325835800en_HK
dc.identifier.scopusauthoridZhu, N=7201449530en_HK
dc.identifier.scopusauthoridChe, CM=7102442791en_HK

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