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Article: Resonance Raman investigation of the short-time photodissociation dynamics of the charge-transfer absorption of the i2-Benzene Complex in Benzene Solution

TitleResonance Raman investigation of the short-time photodissociation dynamics of the charge-transfer absorption of the i2-Benzene Complex in Benzene Solution
Authors
Issue Date2006
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpca
Citation
Journal Of Physical Chemistry A, 2006, v. 110 n. 3, p. 851-860 How to Cite?
AbstractResonance Raman spectra were obtained for the I2-benzene complex in benzene solvent with excitation wavelengths in resonance with the CT-band absorption. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal I-I stretch mode v 18, the nominal symmetric benzene ring stretch mode v 5, and the nominal symmetric CCH bending v 7. There is also a small contribution from the nominal out-of-plane CH oop wag v 15. A preliminary resonance Raman intensity analysis was done, and the results for the I 2-benzene complex were compared to results previously reported for the 1-hexene-I2 complex. We briefly discuss the differences and similarities in the CT-band absorption excitation of an I2-benzene complex relative to those of an I 2-alkene complex. © 2006 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/168006
ISSN
2015 Impact Factor: 2.883
2015 SCImago Journal Rankings: 1.231
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorWeng, KFen_US
dc.contributor.authorShi, Yen_US
dc.contributor.authorZheng, Xen_US
dc.contributor.authorPhillips, DLen_US
dc.date.accessioned2012-10-08T03:14:01Z-
dc.date.available2012-10-08T03:14:01Z-
dc.date.issued2006en_US
dc.identifier.citationJournal Of Physical Chemistry A, 2006, v. 110 n. 3, p. 851-860en_US
dc.identifier.issn1089-5639en_US
dc.identifier.urihttp://hdl.handle.net/10722/168006-
dc.description.abstractResonance Raman spectra were obtained for the I2-benzene complex in benzene solvent with excitation wavelengths in resonance with the CT-band absorption. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal I-I stretch mode v 18, the nominal symmetric benzene ring stretch mode v 5, and the nominal symmetric CCH bending v 7. There is also a small contribution from the nominal out-of-plane CH oop wag v 15. A preliminary resonance Raman intensity analysis was done, and the results for the I 2-benzene complex were compared to results previously reported for the 1-hexene-I2 complex. We briefly discuss the differences and similarities in the CT-band absorption excitation of an I2-benzene complex relative to those of an I 2-alkene complex. © 2006 American Chemical Society.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/jpcaen_US
dc.relation.ispartofJournal of Physical Chemistry Aen_US
dc.titleResonance Raman investigation of the short-time photodissociation dynamics of the charge-transfer absorption of the i2-Benzene Complex in Benzene Solutionen_US
dc.typeArticleen_US
dc.identifier.emailPhillips, DL:phillips@hku.hken_US
dc.identifier.authorityPhillips, DL=rp00770en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/jp055069den_US
dc.identifier.pmid16419981-
dc.identifier.scopuseid_2-s2.0-33644557999en_US
dc.identifier.hkuros161144-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-33644557999&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume110en_US
dc.identifier.issue3en_US
dc.identifier.spage851en_US
dc.identifier.epage860en_US
dc.identifier.isiWOS:000235046100003-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridWeng, KF=12753940600en_US
dc.identifier.scopusauthoridShi, Y=8719070600en_US
dc.identifier.scopusauthoridZheng, X=7404090253en_US
dc.identifier.scopusauthoridPhillips, DL=7404519365en_US

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