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Article: Bis(aliphatic amine)ruthenium(II) porphyrins synthesis, spectroscopy and crystal structure

TitleBis(aliphatic amine)ruthenium(II) porphyrins synthesis, spectroscopy and crystal structure
Authors
KeywordsAliphatic Amine
Characterizeation
Crystal Structure Determination
Ruthenium Porphyrin
Synthesis
Issue Date1997
Citation
Chinese Journal Of Inorganic Chemistry, 1997, v. 13 n. 2, p. 135-145 How to Cite?
AbstractThe synthesis, characterization and reactivities of a series of ruthenium porphyrins including Ru1 (Por) (H2NR)2 and Ru1 (Por) (HNR2)2 [Por = tetraphenyl porphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl) porphyrinato (4-Cl-TPP); R=tert-butyl, isopropyl, cyclohexyl, n-octyl, n-dodecyl, R′ = methyl, ethyl are described. The reaction of Ru (Por) (CO) (MeOH) with m-chloroperoxylbenzoic acid(m-CPBA) followed by treatment of the reaction mixture with excess aliphatic amines readily gave bis (aliphatic amine) ruthenium (II) porphyrins in high yields. All the new complexes have been characterized by 1H NMR, IR, and UV-Visible spectroscopy. The X-ray crystal structure of Ru(TTP) (H2NBu1)2 has been determined. The Ru-N(Por) and Ru-N (H2NBu1) distances in Ru(TTP) (H2NBu1)2 are 0. 2041 nm and 0. 2175 nm, respectively.
Persistent Identifierhttp://hdl.handle.net/10722/167991
ISSN
2015 Impact Factor: 0.488
2015 SCImago Journal Rankings: 0.161
References

 

DC FieldValueLanguage
dc.contributor.authorLi, Zen_US
dc.contributor.authorChe, Cen_US
dc.date.accessioned2012-10-08T03:13:50Z-
dc.date.available2012-10-08T03:13:50Z-
dc.date.issued1997en_US
dc.identifier.citationChinese Journal Of Inorganic Chemistry, 1997, v. 13 n. 2, p. 135-145en_US
dc.identifier.issn1001-4861en_US
dc.identifier.urihttp://hdl.handle.net/10722/167991-
dc.description.abstractThe synthesis, characterization and reactivities of a series of ruthenium porphyrins including Ru1 (Por) (H2NR)2 and Ru1 (Por) (HNR2)2 [Por = tetraphenyl porphyrinato (TPP), meso-tetrakis(p-tolyl)porphyrinato (TTP), meso-tetrakis(4-chlorophenyl) porphyrinato (4-Cl-TPP); R=tert-butyl, isopropyl, cyclohexyl, n-octyl, n-dodecyl, R′ = methyl, ethyl are described. The reaction of Ru (Por) (CO) (MeOH) with m-chloroperoxylbenzoic acid(m-CPBA) followed by treatment of the reaction mixture with excess aliphatic amines readily gave bis (aliphatic amine) ruthenium (II) porphyrins in high yields. All the new complexes have been characterized by 1H NMR, IR, and UV-Visible spectroscopy. The X-ray crystal structure of Ru(TTP) (H2NBu1)2 has been determined. The Ru-N(Por) and Ru-N (H2NBu1) distances in Ru(TTP) (H2NBu1)2 are 0. 2041 nm and 0. 2175 nm, respectively.en_US
dc.languageengen_US
dc.relation.ispartofChinese Journal of Inorganic Chemistryen_US
dc.subjectAliphatic Amineen_US
dc.subjectCharacterizeationen_US
dc.subjectCrystal Structure Determinationen_US
dc.subjectRuthenium Porphyrinen_US
dc.subjectSynthesisen_US
dc.titleBis(aliphatic amine)ruthenium(II) porphyrins synthesis, spectroscopy and crystal structureen_US
dc.typeArticleen_US
dc.identifier.emailChe, C:cmche@hku.hken_US
dc.identifier.authorityChe, C=rp00670en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.scopuseid_2-s2.0-3042894684en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-3042894684&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume13en_US
dc.identifier.issue2en_US
dc.identifier.spage135en_US
dc.identifier.epage145en_US
dc.identifier.scopusauthoridLi, Z=7409079858en_US
dc.identifier.scopusauthoridChe, C=7102442791en_US

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