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Article: Structural Analysis of Five-Coordinate Transition Metal Boryl Complexes with Different d-Electron Configurations

TitleStructural Analysis of Five-Coordinate Transition Metal Boryl Complexes with Different d-Electron Configurations
Authors
Issue Date2004
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 2004, v. 43 n. 8, p. 2541-2547 How to Cite?
AbstractThe site preference of boryl ligands in five-coordinate transition metal boryl complexes has been investigated with the aid of density functional theory calculations. The preferred site for a boryl ligand depends on the electron count of the complex under consideration. Our studies show that the very strong σ-donating boryl ligands choose to occupy coordination sites such that those orbitals accommodating metal d electrons have minimal metal-boryl σ*-antibonding character.
Persistent Identifierhttp://hdl.handle.net/10722/167988
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLam, KCen_US
dc.contributor.authorLam, WHen_US
dc.contributor.authorLin, Zen_US
dc.contributor.authorMarder, TBen_US
dc.contributor.authorNorman, NCen_US
dc.date.accessioned2012-10-08T03:13:47Z-
dc.date.available2012-10-08T03:13:47Z-
dc.date.issued2004en_US
dc.identifier.citationInorganic Chemistry, 2004, v. 43 n. 8, p. 2541-2547en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/10722/167988-
dc.description.abstractThe site preference of boryl ligands in five-coordinate transition metal boryl complexes has been investigated with the aid of density functional theory calculations. The preferred site for a boryl ligand depends on the electron count of the complex under consideration. Our studies show that the very strong σ-donating boryl ligands choose to occupy coordination sites such that those orbitals accommodating metal d electrons have minimal metal-boryl σ*-antibonding character.en_US
dc.languageengen_US
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/icen_US
dc.relation.ispartofInorganic Chemistryen_US
dc.titleStructural Analysis of Five-Coordinate Transition Metal Boryl Complexes with Different d-Electron Configurationsen_US
dc.typeArticleen_US
dc.identifier.emailLam, WH:chsue@hku.hken_US
dc.identifier.authorityLam, WH=rp00719en_US
dc.description.naturelink_to_subscribed_fulltexten_US
dc.identifier.doi10.1021/ic035248een_US
dc.identifier.pmid15074971-
dc.identifier.scopuseid_2-s2.0-3042751738en_US
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-3042751738&selection=ref&src=s&origin=recordpageen_US
dc.identifier.volume43en_US
dc.identifier.issue8en_US
dc.identifier.spage2541en_US
dc.identifier.epage2547en_US
dc.identifier.isiWOS:000220838400016-
dc.publisher.placeUnited Statesen_US
dc.identifier.scopusauthoridLam, KC=8207496000en_US
dc.identifier.scopusauthoridLam, WH=26642862800en_US
dc.identifier.scopusauthoridLin, Z=7404230177en_US
dc.identifier.scopusauthoridMarder, TB=7006433068en_US
dc.identifier.scopusauthoridNorman, NC=7005094633en_US

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